| 000 | 02664nlm1a2200385 4500 | ||
|---|---|---|---|
| 001 | 647660 | ||
| 005 | 20231030040810.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\12806 | ||
| 090 | _a647660 | ||
| 100 | _a20160420a2016 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aPropylene glycol oxidation over silver catalysts: A theoretical study _fM. A. Salaev, O. Kh. Poleshchuk, O. V. Vodyankina |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References.: p. 41-42 (65 tit.)] | ||
| 330 | _aA theoretical interpretation of the mechanism of gas phase propylene glycol oxidation to methylglyoxal over silver catalysts is considered. A model system represented four-atom silver cluster interacting with process adsorbates and/or intermediates has been proposed. Main process routes comprising partial oxidation of the said diol to aldehydes (methylglyoxal, lactaldehyde, acetaldehyde, etc.) as well as diol total oxidation are considered, and the corresponding reaction profiles are represented. The main structural and energetic parameters for the key reaction adsorbates and intermediates and thermochemical data for their main transformations are predicted. The results obtained can be used in further modeling of both vapor- and liquid phase oxidation of propylene glycol over silver catalysts. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tJournal of Molecular Catalysis A: Chemical | ||
| 463 |
_tVol. 417 _v[P. 36-42] _d2016 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aсеребро | |
| 610 | 1 | _aпропиленгликоль | |
| 610 | 1 | _aсеребряные катализаторы | |
| 610 | 1 | _aокисление | |
| 700 | 1 |
_aSalaev _bM. A. |
|
| 701 | 1 |
_aPoleshchuk _bO. Kh. _cchemist _cProfessor-consultant of Yurga technological Institute of Tomsk Polytechnic University, Doctor of chemical sciences _f1947- _gOleg Khemovich _2stltpush _3(RuTPU)RU\TPU\pers\31825 |
|
| 701 | 1 |
_aVodyankina _bO. V. _gOlga Vladimirovna |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bЮргинский технологический институт (филиал) (ЮТИ) _bКафедра естественного научного образования (ЕНО) _h7134 _2stltpush _3(RuTPU)RU\TPU\col\18894 |
| 801 | 2 |
_aRU _b63413507 _c20160420 _gRCR |
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| 856 | 4 | _uhttp://dx.doi.org/10.1016/j.molcata.2016.03.011 | |
| 942 | _cCF | ||