| 000 | 03463nlm1a2200385 4500 | ||
|---|---|---|---|
| 001 | 648212 | ||
| 005 | 20231030040829.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\13369 | ||
| 035 | _aRU\TPU\network\13368 | ||
| 090 | _a648212 | ||
| 100 | _a20160513a2016 k y0rusy50 ca | ||
| 101 | 0 | _aeng | |
| 102 | _aNL | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aA spectroscopic database for water vapor between 5850 and 8340 cm-1 _fS. N. Mikhailenko [et al.] |
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| 203 |
_aText _celectronic |
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| 300 | _aTitle screen | ||
| 320 | _a[References: p. 215-216 (61 tit.)] | ||
| 330 | _aAn accurate and complete empirical spectroscopic database is constructed for natural water in the 5850-8340 cm−1 near infrared region (1.71-1.20 µm). The global list includes more than 46,500 transitions of the six most abundant isotopologues (H216O, H218O, H217O, HD16O, HD17O, HD18O) in natural isotopic abundance with intensity greater than 1×10−29 cm/molecule. All line positions were obtained by difference of empirically determined energy values. These empirical determinations are mostly based on extensive investigations of water vapor spectra by high-sensitivity CRDS complemented with literature data. In particular, the sets of energy levels of the minor isotopologues have been significantly enlarged from very recent analysis of CRDS spectra of D, 18O and 17O enriched water samples. The empirical line positions were associated to experimental intensity values from the literature obtained by FTS for the strong lines and CRDS for weaker lines. The list is made mostly complete by including a large number of weak transitions not yet detected, with empirical positions calculated from empirical levels associated with variational intensities. Air- and self-broadening coefficients and air-induced line shifts have been added to each transition using the most recent version of the algorithm used for the HITRAN and GEISA databases. Examples of comparison of CRDS spectra to simulations based on the HITRAN2012 list illustrate the advantages of our database.The relative merit of experimental and variational line intensities is discussed. A separate line list combining empirical line positions and variational intensities is provided. Future improvements from combination of experimental and variational intensities are suggested. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 |
_tJournal of Quantitative Spectroscopy and Radiative Transfer _d1961- |
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| 463 |
_tVol. 179 _v[P. 198–216] _d2016 |
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| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aэлектронный ресурс | |
| 701 | 1 |
_aMikhailenko _bS. N. _cphysicist _cAssociate Professor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences _f1962- _gSemen Nikolaevich _2stltpush _3(RuTPU)RU\TPU\pers\34035 |
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| 701 | 1 |
_aKassi _bS. |
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| 701 | 1 |
_aMondelain _bD. |
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| 701 | 1 |
_aGamache _bR. R. |
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| 701 | 1 |
_aCampargue _bA. |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bФизико-технический институт (ФТИ) _bКафедра высшей математики (ВМ) _h140 _2stltpush _3(RuTPU)RU\TPU\col\18728 |
| 801 | 1 |
_aRU _b63413507 _c20150611 |
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| 801 | 2 |
_aRU _b63413507 _c20161017 _gRCR |
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| 856 | 4 | _uhttp://dx.doi.org/10.1016/j.jqsrt.2016.03.035 | |
| 942 | _cCF | ||