| 000 | 03117nlm1a2200409 4500 | ||
|---|---|---|---|
| 001 | 648939 | ||
| 005 | 20231030040854.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\14098 | ||
| 090 | _a648939 | ||
| 100 | _a20160610a2016 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aStructure and paramagnetic properties of tris-pivaloyltrifluoracetonate thulium(III) complexes with 18-crown-6 by X-ray analysis and NMR _fS. P. Babailov [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: p. 185 (32 tit.)] | ||
| 330 | _aSynthesis and the crystal structure of a novel complex Tm(III) tris-pivaloyltrifluoracetonate, [Tm2(ptf)6] (I) and Tm(III)-tris-pivaloyltrifluoracetonate-(isopropanol)aqua with 18-crown-6 {[Tm(ptf)3(HOCH(CH3)2)H2O] Ч (18-crown-6)} (II) are reported. A single crystal X-ray diffraction study revealed that complex I has molecular structure which consists of discrete dimeric [Tm2(ptf)6] molecules. Two thulium atoms are located at the 3.7993(2) Е distance. Complex II has molecular structure with hydrogen bonds between oxygen atoms of water molecule and 18-crown-6. Thermogravimetric data evidence the volatility of compound I. It was found by 1H NMR that complexes I, II, [Tm(H2O)(ptf)3] and [Tm(H2O)(ptf)3] Ч (18-crown-6) may be used (due to the substantial temperature dependence of the paramagnetic lanthanide-induced shifts {LIS}) as NMR thermometric sensors for controlling the local temperature in organic media. According to our information this is the first example of a detailed study of the essential temperature dependence of the LIS on 1/T for Tm complexes in organic media. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 |
_tPolyhedron _oScientific Journal |
||
| 463 |
_tVol. 105 _v[P. 178-185] _d2016 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aмолекулярная структура | |
| 610 | 1 | _aкристаллическое состояние | |
| 610 | 1 | _aволатильность | |
| 701 | 1 |
_aBabailov _bS. P. _cchemist _cSenior researcher of Tomsk Polytechnic University _f1960- _gSergey Pavlovich _2stltpush _3(RuTPU)RU\TPU\pers\36566 |
|
| 701 | 1 |
_aStabnikov _bP. A. _gPavel Aleksandrovich |
|
| 701 | 1 |
_aKorolkov _bI. V. _gIljya Viktorovich |
|
| 701 | 1 |
_aPervukhina _bN. V. _gNataljya Viktorovna |
|
| 701 | 0 |
_aKoshcheeva _bO. S. _gOlga Sergeevna |
|
| 701 | 1 |
_aChuykov _bI. P. _gIgor Petrovich |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bФизико-технический институт (ФТИ) _bКафедра химической технологии редких, рассеянных и радиоактивных элементов (№ 43) (ХТРЭ) _h56 _2stltpush _3(RuTPU)RU\TPU\col\18733 |
| 801 | 2 |
_aRU _b63413507 _c20160610 _gRCR |
|
| 856 | 4 | _uhttp://dx.doi.org/10.1016/j.poly.2015.12.014 | |
| 942 | _cCF | ||