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100 _a20160825a2016 k y0engy50 ba
101 0 _aeng
102 _aSG
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aSophisticated and Spontaneous Template-Free Organization of Silica Nanoparticles During Storage
_fN. E. Bogdanchikova [et al.]
203 _aText
_celectronic
300 _aTitle screen
330 _aHierarchical self-assembling of materials represents one of the most appealing subjects in nanoscience, since bottom-up strategies allow for tailor-made synthesis of functional structures in commodities as well as in living systems. Herein we show that nanorings of ca. 10nm silica nanoparticles without any inorganic metal oxide or organic participant are able to spontaneously self-assemble presenting sophisticated forms and hierarchy. It was observed that after synthesis, silica nanoparticles are chaotically distributed but during storage at ambient conditions they spontaneously form self-assembled aggregates with multiplicity of morphologies when a small amount of water is added in the environment. Detailed description of the morphology of such structures by high resolution transmission electron microscope (HRTEM) is presented together with a discussion about the role of water during their spontaneous formation.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tNANO
463 _tVol. 11, iss. 4
_v[10 p.]
_d2016
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
701 1 _aBogdanchikova
_bN. E.
_gNina Evgenjevna
701 1 _aMartynyuk
_bO. A.
_gOksana Anatoljevna
701 1 _aVazquez-Gomez
_bR. L.
_gRoberto
701 1 _aRuiz
_bF.
_gFransisco
701 1 _aHuerta-Saquero
_bA.
_gAlejandro
701 1 _aZepeda
_bT.
_gTrino
701 1 _aPestryakov
_bA. N.
_cChemist
_cProfessor of Tomsk Polytechnic University, Doctor of Chemical Science
_f1963-
_gAleksey Nikolaevich
_2stltpush
_3(RuTPU)RU\TPU\pers\30471
701 1 _aMota-Morales
_bJ. D.
_gJosue
712 0 2 _aНациональный исследовательский Томский политехнический университет (ТПУ)
_bИнститут природных ресурсов (ИПР)
_bКафедра физической и аналитической химии (ФАХ)
_h94
_2stltpush
_3(RuTPU)RU\TPU\col\18656
801 2 _aRU
_b63413507
_c20160825
_gRCR
856 4 _uhttp://dx.doi.org/10.1142/S1793292016500375
942 _cCF