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182 0 _ab
200 1 _aThe promoting effect of pyridine ligands in the Pd-catalysed Heck–Matsuda reaction
_fW. Khodja [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 48 tit.]
330 _aAn efficient Pd-catalyzed arylation reaction of challenging acyclic olefins, in the presence of an organic ligand, has been disclosed. Commercially available cheap pyridine-based ligands are able to promote good to excellent yields for poorly efficient Heck–Matsuda arylation reactions of several allylic alcohols. A wide range of electronically different arenediazonium salts bearing either electron-releasing or withdrawing groups have been used allowing the synthesis of a range of Я-aryl-methoxy-lactols. The catalytic system has been optimised, along with the reaction conditions, in order to achieve remarkable yields in less than 1 h.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tNew Journal of Chemistry
463 _tVol. 40, iss. 10
_v[P. 8855-8862]
_d2016
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
701 1 _aKhodja
_bW.
_gWalid
701 1 _aLeclair
_bA.
_gAlexandre
701 1 _aRull-Barrull
_bJ.
_gJordi
701 1 _aZammattio
_bF.
_gFrancoise
701 1 _aKutonova
_bK. V.
_cchemist
_cEngineer of Tomsk Polytechnic University
_f1990-
_gKsenia Valentinovna
_2stltpush
_3(RuTPU)RU\TPU\pers\31822
701 1 _aTrusova
_bM. E.
_corganic chemist
_cAssociate professor of Tomsk Polytechnic University, Candidate of chemical sciences
_f1982-
_gMarina Evgenievna
_2stltpush
_3(RuTPU)RU\TPU\pers\31823
701 1 _aFelpin
_bF.-Х.
_gFrancois-Xavier
701 1 _aRodriguez
_bZ. M.
_gZubiri Mireia
712 0 2 _aНациональный исследовательский Томский политехнический университет (ТПУ)
_bИнститут физики высоких технологий (ИФВТ)
_bКафедра биотехнологии и органической химии (БИОХ)
_h6810
_2stltpush
_3(RuTPU)RU\TPU\col\18693
801 2 _aRU
_b63413507
_c20161013
_gRCR
856 4 _uhttp://dx.doi.org/10.1039/C6NJ01717G
942 _cCF