| 000 | 02888nlm1a2200433 4500 | ||
|---|---|---|---|
| 001 | 651515 | ||
| 005 | 20231030041037.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\16764 | ||
| 090 | _a651515 | ||
| 100 | _a20161115a2016 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aCH | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aSynthesis, Crystal Structure, and Luminescent Properties of New Zinc(II) and Cadmium(II) Metal-Organic Frameworks Based on Flexible Bis(imidazol-1-yl)alkane Ligands _fM. O. Barsukova [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: 52 tit.] | ||
| 330 | _aNew metal-organic frameworks (MOFs) based on zinc and cadmium ions, terephthalic acid, and flexible ligands 1,5-bis(imidazol-1-yl)pentane or 1,6-bis(imidazol-1-yl)hexane were prepared and characterized by X-ray diffraction, thermorgavimetric analysis and IR spectroscopy. The imidazolyl ligands were prepared by a new robust procedure involving the reaction between imidazole and 1,5-dibromopentane or 1,6-dibromohexane in a superbasic medium (KOH in DMSO). MOFs based on 1,5-bis(imidazol-1-yl)pentane had diamond topology (dia) and are triply interpenetrated. Ligands with longer spacer 1,6-bis(imidazol-1-yl)hexane, terephthalate ions and zinc(II) ions formed five-fold interpenetrated metal-organic framework also with dia topology, while cadmium(II) ions with the same ligands formed eight-connected uninodal net with a very rare self-penetrated topological type ilc and a point symbol 424.5.63. The influence of the chemical composition of MOFs on their photoluminescent properties is investigated and discussed in detail. | ||
| 461 | _tCrystals | ||
| 463 |
_tVol. 6, iss. 10 _v[132, 15 p.] _d2016 |
||
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aимидазол | |
| 610 | 1 | _aпарафин | |
| 610 | 1 | _aцинк | |
| 610 | 1 | _aкадмий | |
| 610 | 1 | _aлюминесценция | |
| 610 | 1 | _aлиганды | |
| 701 | 1 |
_aBarsukova _bM. O. _gMarina Olegovna |
|
| 701 | 1 |
_aGoncharova _bT. V. _gTatjyana Vladimirovna |
|
| 701 | 1 |
_aSamsonenko _bD. G. _gDenis Gennadievich |
|
| 701 | 1 |
_aDybtsev _bD. N. _gDanil Nikolaevich |
|
| 701 | 1 |
_aPotapov _bA. S. _cChemist _cProfessor of Tomsk Polytechnic University, Doctor of chemical sciences _f1981- _gAndrey Sergeevich _2stltpush _3(RuTPU)RU\TPU\pers\33909 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bИнститут физики высоких технологий (ИФВТ) _bКафедра биотехнологии и органической химии (БИОХ) _h6810 _2stltpush _3(RuTPU)RU\TPU\col\18693 |
| 801 | 2 |
_aRU _b63413507 _c20161115 _gRCR |
|
| 856 | 4 | 0 | _uhttp://dx.doi.org/10.3390/cryst6100132 |
| 942 | _cCF | ||