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| 001 | 651806 | ||
| 005 | 20231030041102.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\17068 | ||
| 035 | _aRU\TPU\network\15401 | ||
| 090 | _a651806 | ||
| 100 | _a20161123a2016 k y0engy50 ba | ||
| 101 | 0 |
_aeng _deng |
|
| 102 | _aGB | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aBr2F7− and Br3F10−: peculiar anions showing μ2- and μ3-bridging F-atoms _fS. I. Ivlev [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: p. 12043 (41 tit.)] | ||
| 330 | _aRbCl and CsCl react with BrF3 yielding the corresponding decafluoridotribromates(III), MBr3F10(M = Rb, Cs), which were structurally characterized for the first time. The Br3F10− anion is surprisingly not linear but contains a μ3-bridging fluorine atom and seems to be the first example of μ3-F bridging of Br atoms. The compounds are highly reactive and cannot be handled in glassware. As for the tetrafluoridobromates themselves, they are powerful oxidizers and thus suitable for the dry-chemical recycling of precious metals and additionally feature a significantly higher BrF3 content. | ||
| 461 |
_tChemical Communications _d1989- |
||
| 463 |
_tVol. 52, iss. 81 _v[P. 12040-12043] _d2016 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 701 | 1 |
_aIvlev _bS. I. _gSergey Ivanovich |
|
| 701 | 1 |
_aKarttunen _bA. J. _gAntti |
|
| 701 | 1 |
_aOstvald _bR. V. _cChemical Engineer _cAssociate Professor of Tomsk Polytechnic University, Candidate of chemical sciences _f1980- _gRoman Vyacheslavovich _2stltpush _3(RuTPU)RU\TPU\pers\31221 |
|
| 701 | 1 |
_aKraus _bK. _gKraus |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bИнститут природных ресурсов (ИПР) _bКафедра технологии органических веществ и полимерных материалов (ТОВПМ) _h6832 _2stltpush _3(RuTPU)RU\TPU\col\18659 |
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_aRU _b63413507 _c20161123 _gRCR |
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| 856 | 4 | _uhttp://dx.doi.org/10.1039/C6CC06761A | |
| 942 | _cCF | ||