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090 _a652958
100 _a20170201a2017 k y0engy50 ba
101 0 _aeng
105 _ay z 100zy
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aCoal char oxidation kinetics in air medium
_fA. G. Korotkikh, K. V. Slusarskiy (Slyusarsky), I. V. Sorokin
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 7 tit.]
330 _aStudy of oxidation kinetics for three types of coal char with different carbon content in air is presented. The coal char powders of anthracite, bituminous T-grade coal and 2B-grade lignite with particle size less than 80 [mu]m were tested. The coal char oxidation was researched by isothermal method via simultaneous TG-DSC analyzer Netzsch STA 449 Jupiter F3 in the temperature range of 1000-1200 °C. Measurements were carried out at ambient pressure. Volumetric flow rate of oxidizing medium into analyser chamber was 250 ml/min. Flow consisted of air and argon with volumetric ratio 24/1. Carbon average rate of oxidation reaction at each temperature were defined based on experimental results. Kinetic constants (the frequency factor and activation energy) were defined for Arrhenius equation modified with three submodels: volumetric model, shrinking core model and random pore model. The activation energy values for anthracite are 1,6-1,7 times higher than for chars of bituminous coal and lignite.
461 0 _0(RuTPU)RU\TPU\network\4526
_tMATEC Web of Conferences
463 0 _0(RuTPU)RU\TPU\network\18128
_tVol. 92 : Thermophysical Basis of Energy Technologies (TBET-2016)
_oProceedings of the Conference, October 26-28, 2016, Tomsk, Russia
_fNational Research Tomsk Polytechnic University (TPU) ; eds. G. V. Kuznetsov ; P. A. Strizhak ; A. O. Zhdanova
_v[01020, 5 p.]
_d2017
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _aкинетика окисления
610 1 _aугли
610 1 _aвоздушные среды
610 1 _aполукоксы
610 1 _aанализаторы
610 1 _aтепловые электростанции
610 1 _aтвердые топлива
610 1 _aутилизация
610 1 _aдымовые газы
610 1 _aгазификация
700 1 _aKorotkikh
_bA. G.
_cspecialist in the field of power engineering
_cAssociate Professor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences
_f1976-
_gAleksandr Gennadievich
_2stltpush
_3(RuTPU)RU\TPU\pers\34763
701 1 _aSlusarskiy (Slyusarsky)
_bK. V.
_cspecialist in the field of power engineering
_cassistant of Tomsk Polytechnic University
_f1990-
_gKonstantin Vitalievich
_2stltpush
_3(RuTPU)RU\TPU\pers\35634
701 1 _aSorokin
_bI. V.
_gIvan
712 0 2 _aНациональный исследовательский Томский политехнический университет (ТПУ)
_bЭнергетический институт (ЭНИН)
_bКафедра атомных и тепловых электростанций (АТЭС)
_h118
_2stltpush
_3(RuTPU)RU\TPU\col\18683
801 2 _aRU
_b63413507
_c20170213
_gRCR
856 4 _uhttp://dx.doi.org/10.1051/matecconf/20179201020
856 4 _uhttp://earchive.tpu.ru/handle/11683/36725
942 _cCF