| 000 | 02928nlm1a2200433 4500 | ||
|---|---|---|---|
| 001 | 653681 | ||
| 005 | 20231030041228.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\19175 | ||
| 035 | _aRU\TPU\network\19088 | ||
| 090 | _a653681 | ||
| 100 | _a20170322a2016 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aSK | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aStudy of phenol degradation pathway during electromediated mineralization _fE. V. Zangieva, M. K. Zamanova, O. S. Kukurina |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: p. 576-577 (20 tit.)] | ||
| 330 | _aA new process of electromediated oxidative degradation of phenol and its main intermediate - hydroquinone has been studied. The oxidizers complex has been generated by passing direct current through sulfuric acid solutions containing phenols. To qualitative and quantitative analysis of reaction intermediates a gas chromatography and UV spectroscopy have been used. These analyses have shown total mineralization of toxic products of phenol and hydroquinone and the decay rate constants have maximum values at current density 0.6 A/cm2 . Moreover, the values of pseudo first-order rate constants are comparable to rate constants for non-thermal plasma treatment. According to UVspectroscopy, the main intermediate of phenol oxidation is p-benzoquinone, which has not been identified by GC/MS. In any case, the both phenol and hydroquinone have been successively degraded to carbon dioxide and water at these conditions. | ||
| 333 | _aСвободный доступ из сети Интернет | ||
| 461 | _tPetroleum and Coal | ||
| 463 |
_tVol. 58, iss. 5 _v[P. 573-577] _d2016 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aphenol | |
| 610 | 1 | _akinetics | |
| 610 | 1 | _aфенолы | |
| 610 | 1 | _aгидрохинон | |
| 610 | 1 | _aокисление | |
| 610 | 1 | _aкинетика | |
| 700 | 1 |
_aZangieva _bE. V. _gEkaterina Valentinovna |
|
| 701 | 1 |
_aZamanova _bM. K. _cChemical Engineer _cengineer of Tomsk Polytechnic University _f1983- _gMargarita Karimovna _2stltpush _3(RuTPU)RU\TPU\pers\33834 |
|
| 701 | 1 |
_aKukurina _bO. S. _cchemist _cAssociate Professor of Tomsk Polytechnic University, Candidate of chemical sciences _f1975- _gOlga Sergeevna _2stltpush _3(RuTPU)RU\TPU\pers\31279 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bИнститут природных ресурсов (ИПР) _bКафедра технологии органических веществ и полимерных материалов (ТОВПМ) _h6832 _2stltpush _3(RuTPU)RU\TPU\col\18659 |
| 801 | 2 |
_aRU _b63413507 _c20200217 _gRCR |
|
| 856 | 4 | _uhttp://www.vurup.sk/wp-content/uploads/dlm_uploads/2017/07/pc_6_2016_zagnieva_490.pdf | |
| 942 | _cCF | ||