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100 _a20170426a2017 k y0engy50 ba
101 0 _aeng
102 _aNL
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aExperimental and theoretical study of photo- and electroluminescence of divinyldiphenyl and divinylphenanthrene derivatives
_fL. G. Samsonova [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: p. 64 (33 tit.)]
330 _aElectronic absorption and luminescence spectra of four new compounds of divinyldiphenyl anddivinylphenanthrene derivatives are investigated experimentally in tetrahydrofuran solutions and thin films obtainedby thermal vacuum deposition and by spin coating of these substances embedded into polyvinylcarbazolematrix. Molecular geometry optimizations and electronic spectra have been calculated in the framework of XMCQDPT2/6-31G(d, p) and TDDFT/B3LYP/6-31G (d, p) levels of theory. We have fabricated and studied OLED deviceswith the structure ITO/PEDOT:PSS/NPD/L/Ca/Al and ITO/PEDOT:PSS/PVK + L/Ca, where L is theluminophore. It is demonstrated that the photo-and electroluminescence spectra of divinyldiphenyl are not identicaland undergo strong changes depending on the method of sample preparation.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tSpectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
463 _tVol. 173
_v[P. 59–64]
_d2017
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _aexciplexes
610 1 _aлинейные молекулы
610 1 _aфотолюминесценция
610 1 _aэлектролюминесценция
610 1 _aэксимеры
701 1 _aSamsonova
_bL. G.
_gLyubov Gavrilovna
701 1 _aValiev
_bR. R.
_cchemist
_cAssistant of Tomsk Polytechnic University
_f1983-
_gRashid Rinatovich
_2stltpush
_3(RuTPU)RU\TPU\pers\34114
701 1 _aDegtyarenko
_bK. M.
_gKonstantin Mikhaylovich
701 1 _aSunchugashev
_bD. A.
_gDmitry Andreevich
701 1 _aKukhta
_bI. N.
_gIrina
701 1 _aKukhta
_bA. V.
_gAleksandr
701 1 _aKopylova
_bT. N.
_gTatjyana Nikolaevna
712 0 2 _aНациональный исследовательский Томский политехнический университет (ТПУ)
_bИнститут физики высоких технологий (ИФВТ)
_bКафедра общей химии и химической технологии (ОХХТ)
_h7617
_2stltpush
_3(RuTPU)RU\TPU\col\21253
801 2 _aRU
_b63413507
_c20170426
_gRCR
856 4 _uhttp://dx.doi.org/10.1016/j.saa.2016.08.056
942 _cCF