| 000 | 02099nlm1a2200385 4500 | ||
|---|---|---|---|
| 001 | 654774 | ||
| 005 | 20231030041315.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\20461 | ||
| 035 | _aRU\TPU\network\20146 | ||
| 090 | _a654774 | ||
| 100 | _a20170519a1996 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aHigh time resolution spectroscopy studies of the explosive decomposition of silver azide _fB. P. Aduev [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: p. 1145 (23 tit.)] | ||
| 330 | _aWe have analyzed the existing assumptions about the mechanism of the explosive decomposition of the heavy metal azides. We present here a study of the kinetics of the explosive decomposition of silver azide, initiated by a laser pulse. New effects are identified and studied, including a pre-explosion conductivity and luminescence. On the basis of our results, we conclude that the reaction proceeds by a chain reaction mechanism. In terms of band theory, we propose a model of the primary chain step of the reaction as the creation of a quasilocalized state deep in the valence band with two holes localized at a defect (N30), with impact ionization occurring as they “float up”. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 |
_tRussian Physics Journal _d1965- |
||
| 463 |
_tVol. 39, iss. 11 _v[P. 1135-1145] _d1996 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aспектроскопия | |
| 610 | 1 | _aазид серебра | |
| 701 | 1 |
_aAduev _bB. P. |
|
| 701 | 1 |
_aAluker _bE. D. |
|
| 701 | 1 |
_aBelokurov _bG. M. |
|
| 701 | 1 |
_aZakharov _bYu. A. _cRussian chemist _cDoctor of Chemical Sciences, Professor of Tomsk Polytechnic University _f1938 - _gYuriy Aleksandrovich _2stltpush _3(RuTPU)RU\TPU\pers\38688 |
|
| 701 | 1 |
_aKrechetov _bA. G. |
|
| 801 | 2 |
_aRU _b63413507 _c20170529 _gRCR |
|
| 856 | 4 | 0 | _uhttp://dx.doi.org/10.1007/BF02436156 |
| 942 | _cCF | ||