| 000 | 02961nlm1a2200481 4500 | ||
|---|---|---|---|
| 001 | 654787 | ||
| 005 | 20231030041315.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\20474 | ||
| 035 | _aRU\TPU\network\13922 | ||
| 090 | _a654787 | ||
| 100 | _a20170522a2017 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aUS | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aOligogermanes Containing Only Electron-Withdrawing Substituents: Synthesis and Properties _fK. V. Zaitsev [at al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 330 | _aA series of germanes Ar3GeX, containing electron-withdrawing substituents [Ar = p-FC6H4, 1a–d, 1a (X = Cl), 1b (X = Br), 1c (X = H), 1d (X = NMe2); p-F3CC6H4, 2a–d, 2a (X = Cl), 2b (X = Br), 2c (X = H), 2d (X = NMe2)], was synthesized and used to prepare symmetrical digermanes Ar3Ge–GeAr3, (p-FC6H4)3GeGe(C6H4F-p)3 (3), and (p-F3CC6H4)3GeGe(C6H4CF3-p)3 (4) and trigermane [(p-F3CC6H4)3Ge]2Ge(C6F5)2 (5) by hydrogermolysis reaction. The properties of all compounds were investigated by multinuclear NMR and for oligogermanes by UV/vis and fluorescence spectroscopy, as well as by electrochemical methods. In addition, the molecular structures of 1a, 1b, 2b, 2c, and 3–5 were studied by X-ray diffraction analysis. Compound 5 showed a significantly shifted UV/visible absorption to the red field in comparison with previously described derivatives. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tOrganometallics | ||
| 463 |
_tVol. 36, iss. 2 _v[P. 298–309] _d2017 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aсинтез | |
| 610 | 1 | _aсвойства | |
| 610 | 1 | _aспектроскопия | |
| 610 | 1 | _aэлектрохимические методы | |
| 701 | 1 |
_aZaitsev _bK. V. _gKirill Vasiljevich |
|
| 701 | 1 |
_aLam _bK. _gKevin |
|
| 701 | 0 | _aZhaisan Zhanabil | |
| 701 | 0 | _aSuleimen Yerlan | |
| 701 | 1 |
_aKharcheva _bA. V. _gAnna Viktorovna |
|
| 701 | 1 |
_aTafeenko _bV. A. _gViktor Aleksandrovich |
|
| 701 | 1 |
_aOprunenko _bYu. F. _gYuri |
|
| 701 | 1 |
_aPoleshchuk _bO. Kh. _cchemist _cProfessor-consultant of Yurga technological Institute of Tomsk Polytechnic University, Doctor of chemical sciences _f1947- _gOleg Khemovich _2stltpush _3(RuTPU)RU\TPU\pers\31825 |
|
| 701 | 1 |
_aLermontova _bE. K. _gElena Khimovna |
|
| 701 | 1 |
_aChurakov _bA. V. |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bЮргинский технологический институт (филиал) (ЮТИ) _bКафедра сварочного производства (КСП) _h355 _2stltpush _3(RuTPU)RU\TPU\col\18891 |
| 801 | 2 |
_aRU _b63413507 _c20170522 _gRCR |
|
| 856 | 4 | _uhttp://dx.doi.org/10.1021/acs.organomet.6b00767 | |
| 942 | _cCF | ||