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100 _a20170523a2017 k y0engy50 ba
101 0 _aeng
102 _aUS
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aChanges in the composition of the bituminous components of valley peat under stimulated microbial action
_fL. I. Svarovskaya [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: p. 77 (19 tit.)]
330 _aThe stimulated microbial oxidation of valley peat by aboriginal microflora was experimentally studied for evaluating the participation of microflora in the conversion of organic matter in present-day swamp deposits. The esters of n-carboxylic acids, triphenyl phosphates, C14–C31n-alkanes, squalene, methyldehydroabietate, steroids, and pentacyclic terpenoids with the predominance of unsaturated structures mainly with the alcohol groups were identified in the composition of the bituminous components of microflora. It was found that the absolute concentrations of all of the identified groups of organic compounds in peat considerably decreased as a result of biodegradation. The relative concentrations of high-molecularweight (C27–C34) homologues and C16–C20 homologues predominant in bacteria in the composition of peat n-alkanes increased. Steroids and pentacyclic triterpenoids were enriched in unsaturated structures and compounds with the alcohol groups. Aldehydes disappeared from the composition of acyclic compounds. The fractions of palmitic acid derivatives in methyl ethers and isoprenoid structures in alkanones sharply increased.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tSolid Fuel Chemistry
463 _tVol. 51, iss. 2
_v[Р. 67-77]
_d2017
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _aторф
610 1 _aмикрофлора
610 1 _aорганические вещества
610 1 _aторфяные болота
701 1 _aSvarovskaya
_bL. I.
_gLidiya Ivanovna
701 1 _aSerebrennikova
_bO. V.
_cgeochemist
_cProfessor of Tomsk Polytechnic University, Doctor of chemical sciences
_f1949-
_gOlga Viktorovna
_2stltpush
_3(RuTPU)RU\TPU\pers\30954
701 1 _aDuchko
_bM. A.
_cchemist
_cassistant of Tomsk Polytechnic University
_f1990-
_gMariya Aleksandrovna
_2stltpush
_3(RuTPU)RU\TPU\pers\35855
701 1 _aStrelnikova
_bE. B.
701 1 _aRusskikh
_bI. V.
_gIrina Vladimirovna
712 0 2 _aНациональный исследовательский Томский политехнический университет (ТПУ)
_bИнститут природных ресурсов (ИПР)
_bКафедра геологии и разведки полезных ископаемых (ГРПИ)
_h2181
_2stltpush
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712 0 2 _aНациональный исследовательский Томский политехнический университет (ТПУ)
_bИнститут природных ресурсов (ИПР)
_bКафедра химической технологии топлива и химической кибернетики (ХТТ)
_h105
_2stltpush
_3(RuTPU)RU\TPU\col\18665
801 2 _aRU
_b63413507
_c20170908
_gRCR
856 4 _uhttp://dx.doi.org/10.3103/S0361521917020094
942 _cCF