| 000 | 03812nlm1a2200481 4500 | ||
|---|---|---|---|
| 001 | 654871 | ||
| 005 | 20231030041318.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\20569 | ||
| 035 | _aRU\TPU\network\20508 | ||
| 090 | _a654871 | ||
| 100 | _a20170525a2017 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aGold and Silver Catalysts for Liquid Phase n-Octanol Oxidation: Effect of Promoters _fYu. I. Kotolevich [et al.] |
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| 203 |
_aText _celectronic |
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| 300 | _aTitle screen | ||
| 330 | _aBackground: In comparison with these platinum group metal catalysts, supported nano gold catalysts have emerged as a new type of catalysts highly active at low temperature and selective for the aerobic oxidation of alcohols. But catalytic data and detailed characterizations of the Au-Ag bimetal catalytic system are not available up to date.Objective: This work is aimed to develop bimetallic AuAg-based heterogeneous catalysts for liquid phase selective oxidation of n-octanol. Modification of the titania support with transition metal additives were used as tools for transforming active species.Method: Catalytic tests in n-octanol liquid-phase oxidation at 80 °C. Catalyst characterization by Transmission electron microscopy, X-ray diffraction, plasma atomic emission spectroscopy, X-ray photoelectron spectroscopy, EXAFS and UV-visible spectroscopy.Results and Conclusion: Bimetallic AuAg catalysts supported on titania are moderately active for liquid phase selective oxidation of n-octanol. Formation of Au-Ag alloy was observed. Their activity may be increased by modification of the support with donor additives (La, Mg), while acceptor additives (Ce, Fe) decreased it. The addition of La, that inhibits the formation of Au-Ag alloy, provides the highest activity and the highest stability of reaction rate with run time in either as prepared and red-ox treated forms, which implies that it stabilizes the active centers in its optimal electronic state. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 |
_tCurrent Organic Synthesis _d2004- |
||
| 463 |
_tVol. 14, iss. 3 _v[P. 323 - 331] _d2017 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aзолото | |
| 610 | 1 | _aсеребро | |
| 610 | 1 | _aкатализаторы | |
| 610 | 1 | _aжидкофазное окисление | |
| 610 | 1 | _aпромоторы | |
| 701 | 1 |
_aKotolevich _bYu. I. _gYuliya |
|
| 701 | 1 |
_aKolobova _bE. N. _cChemical Engineer _cdesign engineer of Tomsk Polytechnic University _f1989- _gEkaterina Nikolaevna _2stltpush _3(RuTPU)RU\TPU\pers\34488 |
|
| 701 | 1 |
_aPestryakov _bA. N. _cChemist _cProfessor of Tomsk Polytechnic University, Doctor of Chemical Science _f1963- _gAleksey Nikolaevich _2stltpush _3(RuTPU)RU\TPU\pers\30471 |
|
| 701 | 1 |
_aCabrera _bO. J. E. _gOrtega Jesus Efren |
|
| 701 | 1 |
_aBogdanchikova _bN. E. _gNina Evgenjevna |
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| 701 | 1 |
_aCortes _bC. V. _gCorberan |
|
| 701 | 1 |
_aKhramov _bEvgeny _gE. A. |
|
| 701 | 1 |
_aZubavichus _bYa. V. _gYan Vitautasovich |
|
| 701 | 1 |
_aZanella _bRodolfo _gR. A. |
|
| 701 | 1 |
_aPakrieva _bE. G. _cChemical Engineer _cEngineer of Tomsk Polytechnic University _f1989- _gEkaterina Germanovna _2stltpush _3(RuTPU)RU\TPU\pers\33273 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bИнститут природных ресурсов (ИПР) _bКафедра физической и аналитической химии (ФАХ) _h94 _2stltpush _3(RuTPU)RU\TPU\col\18656 |
| 801 | 2 |
_aRU _b63413507 _c20170525 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.2174/1570179413666161031113854 | |
| 942 | _cCF | ||