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100 _a20170525a1992 k y0engy50 ba
101 0 _aeng
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aOxidation, bromination, and methylenation of carbazole and (E)-3-(2-phenylethenyl)carbazole with HBr/DMSO
_fM. S. Yusubov [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 8 tit.]
330 _aIt is shown that oxidation of (E)-3-(2-phenylethenyl)-9-methylcarbazole with HBr/DMSO leads to the formation of 1-(6-bromo-9-methylcarbazol-3-yl)-2-phenylethane-1,2-dione. In the case of (E)-3-(2-phenylethenyl)carbazole, methylenation occurs with formation of 9,9′-bis[3-(2-phenylethane-1,2-dionyl)-6-bromocarbazolyl]methane in addition to oxidation of the double bond and bromination of the phenyl ring. This reagent can also be successfully used for the preparative bromination and methylenation of certain carbazoles.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tChemistry of Heterocyclic Compounds
463 _tVol. 28, iss. 11
_v[P. 1260-1263]
_d1992
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
701 1 _aYusubov
_bM. S.
_cchemist
_cProfessor of Tomsk Polytechnic University, Doctor of chemical sciences
_f1961-
_gMekhman Suleiman-Ogly (Suleimanovich)
_2stltpush
_3(RuTPU)RU\TPU\pers\31833
701 1 _aFilimonov
_bV. D.
_cRussian chemist
_cProfessor of the TPU
_f1945-
_gViktor Dmitrievich
_2stltpush
_3(RuTPU)RU\TPU\pers\26423
701 1 _aKrasnokutskaya
_bE. A .
_corganic chemist
_cProfessor of Tomsk Polytechnic University, Doctor of chemical sciences
_f1966-
_gElena Aleksandrovna
_2stltpush
_3(RuTPU)RU\TPU\pers\31829
701 1 _aKovaleva
_bL. F.
801 2 _aRU
_b63413507
_c20170525
_gRCR
856 4 _uhttp://dx.doi.org/10.1007/BF00532073
942 _cCF