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100 _a20171011a2017 k y0engy50 ba
101 0 _aeng
102 _aNL
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aFirst rotational analysis of the (111) and (021) vibrational state of S16O18O from the “hot” ν1+ν2+ν3−ν2 and 2ν2+ν3−ν2bands
_fO. N. Ulenikov [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: p. 102-103 (40 tit.)]
330 _aThe rotational structure of the (111) and (021) vibrational states is determined for the first time from the high resolution analysis of the ν1+ν2+ν3−ν2 and 2ν2+ν3−ν2 “hot” bands. The 480 and 74 transitions of these bands (Jmax/Kamax = 45/14 and 15/12 respectively) were assigned in the spectra, which have been recorded with the Bruker IFS 120 Fourier transform infrared (FTIR) spectrometer. A weighted fit analysis allowed us to generate a set of 5 fitted parameters for the (111) state and 4 fitted parameters for the (021) state. Calculation with the 9 parameters, obtained from the fit, reproduces the initial 363 energy values (about 550 assigned experimental transitions) of two vibrational states with the drms deviations of 3.2×10−4 cm−1, which is comparable with the experimental uncertainties of very weak transitions of the ν1+ν2+ν3−ν2 and 2ν2+ν3−ν2 “hot” bands in our experiment.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tJournal of Quantitative Spectroscopy and Radiative Transfer
463 _tVol. 202
_v[P. 98-103]
_d2017
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _a32S16O18O молекула
610 1 _aгорячие группы
610 1 _aпараметры
610 1 _aвращательный анализ
610 1 _aколебательные состояния
610 1 _aдвуокись серы
701 1 _aUlenekov (Ulenikov)
_bO. N.
_cphysicist
_cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences
_f1949-
_gOleg Nikolaevich
_2stltpush
_3(RuTPU)RU\TPU\pers\34331
701 1 _aGromova
_bO. V.
_cphysicist
_cEngineer-Researcher of Tomsk Polytechnic University, Candidate of physical and mathematical sciences
_f1982-
_gOlga Vasilievna
_2stltpush
_3(RuTPU)RU\TPU\pers\34333
701 1 _aBekhtereva
_bE. S.
_cphysicist
_cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences
_f1974-
_gElena Sergeevna
_2stltpush
_3(RuTPU)RU\TPU\pers\34450
701 1 _aZyatkova (Ziatkova)
_bA. G.
_cPhysicist
_cEngineer of the Department of Tomsk Polytechnic University
_f1991-
_gAnastasiya Georgievna
_2stltpush
_3(RuTPU)RU\TPU\pers\37482
701 1 _aСклярова
_bЕ. А.
_cфизик
_cдоцент Томского политехнического университета, кандидат педагогических наук
_f1972-
_gЕлена Александровна
_2stltpush
_3(RuTPU)RU\TPU\pers\24507
701 1 _aKuznetsov
_bS. I.
_cphysicist
_cassociate professor of Tomsk polytechnic university, candidate of technical sciences (PhD)
_f1952-
_gSergey Ivanovich
_2stltpush
_3(RuTPU)RU\TPU\pers\30071
701 1 _aSydow
_bC.
_gChristian
701 1 _aBauerecker
_bS.
_gSigurd
712 0 2 _aНациональный исследовательский Томский политехнический университет (ТПУ)
_bФизико-технический институт (ФТИ)
_bКафедра общей физики (ОФ)
_h136
_2stltpush
_3(RuTPU)RU\TPU\col\18734
801 2 _aRU
_b63413507
_c20171011
_gRCR
856 4 _uhttps://doi.org/10.1016/j.jqsrt.2017.07.029
942 _cCF