| 000 | 03063nlm1a2200481 4500 | ||
|---|---|---|---|
| 001 | 655921 | ||
| 005 | 20231030041406.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\22261 | ||
| 090 | _a655921 | ||
| 100 | _a20171012a2017 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aHigh resolution Fourier transform infrared spectroscopy of the ground state, ν3,2ν3 and ν4 levels of 13CHF3 _fI. B. Bolotova [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: p. 104 (53 tit.)] | ||
| 330 | _aWe report high resolution ([delta]v<=0.001cm-1) Fourier Transform Infrared (FTIR) spectra of the trifluoromethane (fluoroform) isotopomer 13CHF3 including results from synchrotron based spectroscopy at the Swiss light source (SLS). The analysis is extended to the pure rotational spectra in the Terahertz (far-infrared) range (15-100 cm−1, [delta]vWHM=0.0006cm-1), the v3fundamental (v0=695.292cm-1), the associated “hot” band 2v3-v3 providing information on the level 2v3 (v0=1389.807cm-1) and the v4 fundamental (v0=1369.013cm-1) coupled to 2ν3. The results are discussed in relation to the 13C isotope effect on the vibrational quantum dynamics as derived by theory and in relation to fluoroform as a greenhouse gas. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 |
_tJournal of Molecular Spectroscopy _d1957- |
||
| 463 |
_tVol. 337 _v[P. 96-104] _d2017 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _afluoroform | |
| 610 | 1 | _ahigh resolution infrared spectroscopy | |
| 610 | 1 | _aFTIR | |
| 610 | 1 | _aTHz | |
| 610 | 1 | _aинфракрасная спектроскопия | |
| 610 | 1 | _aИК-Фурье спектроскопия | |
| 610 | 1 | _aвращательные спектры | |
| 701 | 1 |
_aBolotova _bI. B. _cphysicist _cTechnician of Tomsk Polytechnic University _f1989- _gIrina Batorovna _2stltpush _3(RuTPU)RU\TPU\pers\34081 |
|
| 701 | 1 |
_aUlenekov (Ulenikov) _bO. N. _cphysicist _cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences _f1949- _gOleg Nikolaevich _2stltpush _3(RuTPU)RU\TPU\pers\34331 |
|
| 701 | 1 |
_aBekhtereva _bE. S. _cphysicist _cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences _f1974- _gElena Sergeevna _2stltpush _3(RuTPU)RU\TPU\pers\34450 |
|
| 701 | 1 |
_aAlbert _bS. _gSieghard |
|
| 701 | 0 | _aChen Ziqiu | |
| 701 | 1 |
_aHollenstein _bH. A. _gHans |
|
| 701 | 1 |
_aZindel _bD. _gDaniel |
|
| 701 | 1 |
_aQuack _bM. _gMartin |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bФизико-технический институт (ФТИ) _bКафедра общей физики (ОФ) _h136 _2stltpush _3(RuTPU)RU\TPU\col\18734 |
| 801 | 2 |
_aRU _b63413507 _c20171012 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.1016/j.jms.2017.05.003 | |
| 942 | _cCF | ||