| 000 | 03005nlm1a2200481 4500 | ||
|---|---|---|---|
| 001 | 655967 | ||
| 005 | 20231030041408.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\22307 | ||
| 090 | _a655967 | ||
| 100 | _a20171016a2017 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aMolecular structure and paramagnetic properties of bis-diisobutyldithiophosphinate complexes of Europium(III), Ytterbium(III) and Lutetium(III) with 2,2-bipyridyl using NMR _fS. P. Babailov [et al.] |
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| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: p. 318 (15 tit.)] | ||
| 330 | _aThe features of the molecular structure of Ln containing complexes with the dithiophosphinate R2PS2- (R = i-Bu) and 2,2′-bipyridyl ligands [Ln(2,2′-bipyridyl)((i-Bu)2PS2)2(NO3)] {where Ln = Eu3+(I), Yb3+(II) and Lu3+(III)} in CDCl3 have been studied by 1H NMR techniques. These complexes are of interest due to the prospect of using some of them as fluorescent sensors for biology and medicine. The analysis of the structural parameters found by NMR testifies that the 2,2′-bipyridyl and (i-Bu)2PS2-anions are in the first coordination sphere of a Ln cation. The results obtained are consistent with the X-ray studies of the molecular structure of related complex with Tm3+ in the crystalline phase. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tPolyhedron | ||
| 463 |
_tVol. 134 _v[P. 316-318] _d2017 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _alanthanide-induced shifts (LIS) | |
| 610 | 1 | _acrystal-field independent method of LIS analysis | |
| 610 | 1 | _afluorescent sensors | |
| 610 | 1 | _achelating ligands | |
| 610 | 1 | _anon-aqueous solutions | |
| 610 | 1 | _aсдвиги | |
| 610 | 1 | _aлантаниды | |
| 610 | 1 | _aкристаллический независимый метод анализа | |
| 610 | 1 | _aлюминесцентные датчики | |
| 610 | 1 | _aхелатирующие лиганды | |
| 610 | 1 | _aневодные растворы | |
| 701 | 1 |
_aBabailov _bS. P. _cchemist _cSenior researcher of Tomsk Polytechnic University _f1960- _gSergey Pavlovich _2stltpush _3(RuTPU)RU\TPU\pers\36566 |
|
| 701 | 1 |
_aZapolotsky _bE. N. _gEvgeny Nikolaevich |
|
| 701 | 1 |
_aFomin _bE. S. _gEduard Stanislavovich |
|
| 701 | 1 |
_aQu _bYa. _gYanyang |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bФизико-технический институт (ФТИ) _bКафедра химической технологии редких, рассеянных и радиоактивных элементов (№ 43) (ХТРЭ) _h56 _2stltpush _3(RuTPU)RU\TPU\col\18733 |
| 801 | 2 |
_aRU _b63413507 _c20171016 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.1016/j.poly.2017.05.047 | |
| 942 | _cCF | ||