| 000 | 03938nlm0a2200421 4500 | ||
|---|---|---|---|
| 001 | 656439 | ||
| 005 | 20231030041428.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\22880 | ||
| 090 | _a656439 | ||
| 100 | _a20171114d2017 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aNL | ||
| 105 | _ay z 100zy | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aInfluence of alkylaromatic hydrocarbons on the efficiency of linear alkylbenzene sulfonic acid synthesis _fE. D. Ivanchina [et al.] |
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| 203 |
_aText _celectronic |
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| 300 | _aTitle screen | ||
| 320 | _a[References: 45 tit.] | ||
| 330 | _aASA is the main ingredient of many commercial formulations for industrial and domestic synthetic detergents. Studying the work of the technological equipment that is used for manufacturing of the linear ASA allow us to conclude that alkylaromatic hydrocarbons in the product flow to hydrogenation reactor have significant impact on all technological stages. The aim of this work was to estimate the quantitative impact of alkyl components on ASA manufacturing efficiency and to improve the performance of the main equipment. The performed infrared (IR) and gas chromatography–mass spectrometry (GC–MS) analysis of the linear alkylbenzenes (LAB) and ASA samples indicate that the viscous components are tetralines and sultones as a part of unsulphonated matter. The developed mathematical model was used to reveal the following results and regularities of equipment modes: if the hydrogen/feedstock molar ratio at dehydrogenation stage equals 6/1, it is less optimal due to coke formation and requires increasing water supply. An increase of aromatics content in alkylation product flow leads to an increase in HF flow rate to the regeneration column. The optimal SO3/LAB molar ratio increases along with content of aromatics in raw materials. The developed model of sulfonation process predicts the duration of reactor inter-washing period. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tChemical Engineering Journal | ||
| 463 |
_tVol. 329 : XXII International conference on Chemical Reactors CHEMREACTOR-22, 1 December 2017 _v[P. 250-261] _d2017 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aалкилбензолы | |
| 610 | 1 | _aсульфоновые кислоты | |
| 610 | 1 | _aвысоковязкие среды | |
| 701 | 1 |
_aIvanchina _bE. D. _cchemist _cProfessor of Tomsk Polytechnic University, Doctor of technical sciences _f1951- _gEmilia Dmitrievna _2stltpush _3(RuTPU)RU\TPU\pers\31274 |
|
| 701 | 1 |
_aIvashkina _bE. N. _cChemical Engineer _cAssociate Professor of Tomsk Polytechnic University, Candidate of technical science _f1983- _gElena Nikolaevna _2stltpush _3(RuTPU)RU\TPU\pers\31275 |
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| 701 | 1 |
_aDolganova _bI. O. _cchemist _cAssociate Scientist of Tomsk Polytechnic University, postgraduate student, candidate of technical Sciences _f1988- _gIrena Olegovna _2stltpush _3(RuTPU)RU\TPU\pers\31271 |
|
| 701 | 1 |
_aFrantsina _bE. V. _cChemical Engineer _cAssociate Professor of Tomsk Polytechnic University, Candidate of technical sciences _f1985- _gEvgeniya Vladimirovna _2stltpush _3(RuTPU)RU\TPU\pers\32193 |
|
| 701 | 1 |
_aDolganov _bI. M. _cChemical Engineer _cEngineer of Tomsk Polytechnic University _f1987- _gIgor Mikhailovich _2stltpush _3(RuTPU)RU\TPU\pers\32216 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bИнститут природных ресурсов (ИПР) _bКафедра химической технологии топлива и химической кибернетики (ХТТ) _h105 _2stltpush _3(RuTPU)RU\TPU\col\18665 |
| 801 | 2 |
_aRU _b63413507 _c20171114 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.1016/j.cej.2017.06.032 | |
| 942 | _cCF | ||