000 | 02214nlm1a2200409 4500 | ||
---|---|---|---|
001 | 656658 | ||
005 | 20231030041439.0 | ||
035 | _a(RuTPU)RU\TPU\network\23103 | ||
035 | _aRU\TPU\network\23102 | ||
090 | _a656658 | ||
100 | _a20171130a2007 k y0engy50 ba | ||
101 | 0 | _aeng | |
135 | _adrcn ---uucaa | ||
181 | 0 | _ai | |
182 | 0 | _ab | |
200 | 1 |
_a1,3-Diiodo-5,5-dimethylhydantoin-An efficient reagent for iodination of aromatic compounds _fV. K. Chaikovskii [et al.] |
|
203 |
_aText _celectronic |
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300 | _aTitle screen | ||
320 | _a[References: 14 tit.] | ||
330 | _a1,3-Diiodo-5,5-dimethylhydantoin in organic solvents successfully iodinates alkylbenzenes, aromatic amines, and phenyl ethers. The reactivity of electrophilic iodine is controlled by acidity of the medium. Superelectrophilic iodine generated upon dissolution of 1,3-diiodo-5,5-dimethylhydantoin in sulfuric acid readily reacts with electron-deficient arenes at 0 to 20°C with formation of the corresponding iodo derivatives in good yields. The structure of electrophilic iodine species generated from 1,3-diiodo-5,5- dimethylhydantoin in sulfuric acid is discussed. | ||
333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
461 |
_tRussian Journal of Organic Chemistry _oScientific Journal _d2001- |
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463 |
_tVol. 43, iss. 9 _v[P. 1291-1296] _d2007 |
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610 | 1 | _aэлектронный ресурс | |
610 | 1 | _aтруды учёных ТПУ | |
610 | 1 | _aреагенты | |
610 | 1 | _aиодирование | |
610 | 1 | _aароматические соединения | |
610 | 1 | _aсерная кислота | |
701 | 1 |
_aChaikovskii _bV. K. _cchemist _cProfessor of Tomsk Polytechnic University, Doctor of chemical sciences _f1951- _gVitold Kazimirovich _2stltpush _3(RuTPU)RU\TPU\pers\31821 |
|
701 | 1 |
_aFilimonov _bV. D. _cRussian chemist _cProfessor of the TPU _f1945- _gViktor Dmitrievich _2stltpush _3(RuTPU)RU\TPU\pers\26423 |
|
701 | 1 |
_aFunk _bA. A. |
|
701 | 1 |
_aSkorokhodov _bV. I. |
|
701 | 1 |
_aOgorodnikov _bV. D. |
|
801 | 2 |
_aRU _b63413507 _c20171130 _gRCR |
|
856 | 4 | _uhttp://dx.doi.org/10.1134/S1070428007090060 | |
942 | _cCF |