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101 0 _aeng
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _a1,3-Diiodo-5,5-dimethylhydantoin-An efficient reagent for iodination of aromatic compounds
_fV. K. Chaikovskii [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 14 tit.]
330 _a1,3-Diiodo-5,5-dimethylhydantoin in organic solvents successfully iodinates alkylbenzenes, aromatic amines, and phenyl ethers. The reactivity of electrophilic iodine is controlled by acidity of the medium. Superelectrophilic iodine generated upon dissolution of 1,3-diiodo-5,5-dimethylhydantoin in sulfuric acid readily reacts with electron-deficient arenes at 0 to 20°C with formation of the corresponding iodo derivatives in good yields. The structure of electrophilic iodine species generated from 1,3-diiodo-5,5- dimethylhydantoin in sulfuric acid is discussed.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tRussian Journal of Organic Chemistry
_oScientific Journal
_d2001-
463 _tVol. 43, iss. 9
_v[P. 1291-1296]
_d2007
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _aреагенты
610 1 _aиодирование
610 1 _aароматические соединения
610 1 _aсерная кислота
701 1 _aChaikovskii
_bV. K.
_cchemist
_cProfessor of Tomsk Polytechnic University, Doctor of chemical sciences
_f1951-
_gVitold Kazimirovich
_2stltpush
_3(RuTPU)RU\TPU\pers\31821
701 1 _aFilimonov
_bV. D.
_cRussian chemist
_cProfessor of the TPU
_f1945-
_gViktor Dmitrievich
_2stltpush
_3(RuTPU)RU\TPU\pers\26423
701 1 _aFunk
_bA. A.
701 1 _aSkorokhodov
_bV. I.
701 1 _aOgorodnikov
_bV. D.
801 2 _aRU
_b63413507
_c20171130
_gRCR
856 4 _uhttp://dx.doi.org/10.1134/S1070428007090060
942 _cCF