| 000 | 03135nlm1a2200469 4500 | ||
|---|---|---|---|
| 001 | 656796 | ||
| 005 | 20231030041444.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\23276 | ||
| 090 | _a656796 | ||
| 100 | _a20171213a2017 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aDE | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aWater Oxidation by In Situ Generated [Ru”(OH2)(NC[NHC]O)(pic)2]+ _fWei Su [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: p. 2310 (21 tit.)] | ||
| 330 | _aA dinuclear ruthenium complex [R''(NC[NHC]O)(pic)2]22+ (2) was firstly prepared and characterized spectroscopically and electrochemically. Instead of the conventional ligand exchange, complex 2dissociates in situ to afford two single-site Ru aqua complexes, [Ru''(OH2)(NC[NHC]O)(pic)2]+, which mediates water oxidation through proton-coupled electron transfer events. In electrokinetic studies, complex 2 demonstrated a TOF of 150.3 s−1 comparable to those state-of-the-art catalysts at neutral conditions. TONs of 2173 and 217 were attained in chemical and photochemical water oxidation when 2 was used as a catalyst, exhibiting good stability. Notably, a TOF of 1.3 s−1 was achieved at CAN-driven water oxidation, which outperformed most of the reported single-site Ru complexes, indicating that complex 2 is one of most active water oxidation catalysts (WOCs) to date. The unique coordination configuration and outstanding catalytic performance of complex 2 might shed light on the design of novel molecular WOCs. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 |
_tChemistry - An Asian Journal _d2006- |
||
| 463 |
_tVol. 12, iss. 17 _v[С. 2304–2310] _d2017 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aвода | |
| 610 | 1 | _aокисление | |
| 610 | 1 | _aкоординационная химия | |
| 610 | 1 | _aэлектрохимия | |
| 610 | 1 | _aфотокатализ | |
| 610 | 1 | _aрутений | |
| 701 | 0 | _aWei Su | |
| 701 | 0 | _aKui Zhou | |
| 701 | 1 |
_aCai _bF. _gFanglin |
|
| 701 | 0 | _aCheng Chen | |
| 701 | 1 |
_aBibimaryam _bM. _gMousavi |
|
| 701 | 0 |
_aChaemchuen _bS. _cchemist-technologist _cresearcher at Tomsk Polytechnic University _f1984- _gSomboon _2stltpush _3(RuTPU)RU\TPU\pers\42620 |
|
| 701 | 1 |
_aVerpoort _bF. V. K. _cChemical Engineer _cProfessor of Tomsk Polytechnic University, doctor of chemical Sciences _f1963- _gFrensis Valter Kornelius _2stltpush _3(RuTPU)RU\TPU\pers\35059 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bИнститут природных ресурсов (ИПР) _bКафедра технологии органических веществ и полимерных материалов (ТОВПМ) _h6832 _2stltpush _3(RuTPU)RU\TPU\col\18659 |
| 801 | 2 |
_aRU _b63413507 _c20181224 _gRCR |
|
| 856 | 4 | _uhttp://dx.doi.org/10.1002/asia.201700837 | |
| 942 | _cCF | ||