| 000 | 02976nlm1a2200469 4500 | ||
|---|---|---|---|
| 001 | 656819 | ||
| 005 | 20231030041445.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\23299 | ||
| 090 | _a656819 | ||
| 100 | _a20171213a2017 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aInfluence of lactic acid on the catalytic performance of MDABCO for ring-opening polymerization of l-lactide _fLuo Zhixiong [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: p. 20-21 (42 tit.)] | ||
| 330 | _aA series of metal organic frameworks (MOFs) MDABCO (M = Co, Ni, Cu, Zn; DABCO = 1,4-diazabicyclo[2.2.2]octane) are utilized as catalysts for the bulk ring-opening polymerization of l-lactide. The catalytic activity varies in the order CuDABCO, NiDABCO < ZnDABCO, CoDABCO. By adding lactic acid, we unexpectedly observed enhanced catalytic activity. The combined use of lactic acid and ZnDABCO during polymerization results in a highly active polymerization system, along with the gradual change of MOFs structure caused by an increased acid concentration. Compared to related homogeneous fragments, such as zinc nitrate and 1,4-diazabicyclo[2.2.2]octane, ZnDABCO is found to afford highly isotactic polylactide, which would be ascribed to the unique structural properties of MOFs. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tApplied Catalysis A: General | ||
| 463 |
_tVol. 546 _v[P. 15–21] _d2017 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aRing-opening polymerization | |
| 610 | 1 | _apolylactide | |
| 610 | 1 | _aMDABCO MOFs | |
| 610 | 1 | _alactic acid | |
| 610 | 1 | _aheterogeneous catalysis | |
| 610 | 1 | _aполимеризация | |
| 610 | 1 | _aполилактиды | |
| 610 | 1 | _aмолочная кислота | |
| 610 | 1 | _aгетерогенный катализ | |
| 701 | 0 | _aLuo Zhixiong | |
| 701 | 0 |
_aChaemchuen _bS. _cchemist-technologist _cresearcher at Tomsk Polytechnic University _f1984- _gSomboon _2stltpush _3(RuTPU)RU\TPU\pers\42620 |
|
| 701 | 0 | _aZhou Kui | |
| 701 | 1 |
_aGonzalez _bA. A. _gAndres Alvarado |
|
| 701 | 1 |
_aVerpoort _bF. V. K. _cchemist-technologist _cProfessor of Tomsk Polytechnic University, doctor of chemical Sciences _f1963- _gFrensis Valter Kornelius _2stltpush _3(RuTPU)RU\TPU\pers\35059 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bИнститут природных ресурсов (ИПР) _bКафедра технологии органических веществ и полимерных материалов (ТОВПМ) _h6832 _2stltpush _3(RuTPU)RU\TPU\col\18659 |
| 801 | 2 |
_aRU _b63413507 _c20181224 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.1016/j.apcata.2017.08.007 | |
| 942 | _cCF | ||