| 000 | 03117nlm1a2200421 4500 | ||
|---|---|---|---|
| 001 | 656820 | ||
| 005 | 20231030041445.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\23300 | ||
| 090 | _a656820 | ||
| 100 | _a20171213a2017 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aGB | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aUltrasensitive and reproducible SERS platform of coupled Ag grating with multibranched Au nanoparticles _fE. Kalachyova [et al.] |
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| 203 |
_aText _celectronic |
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| 300 | _aTitle screen | ||
| 330 | _aSurface-enhanced Raman scattering (SERS) spectroscopy is an extremely sensitive analytical technique that is capable of identifying the vibration signatures of target molecules up to single-molecule sensitivity. In this work, the ultrahigh sensitivity of SERS has been achieved through the immobilization of sharp-edges specific nanoparticles – so-called gold multibranched NPs (AuMs) on the silver grating surface through the biphenyl dithiol. This approach allows combining the extremely high SERS enhancement factor (better than that in the case of AuMs immobilized on the flat Ag film) with perfect reproducibility of Raman signals. The grating was created on the polymer substrate using the excimer laser modification and further metal deposition and has an “active” area 5 ? 10 mm2, enabling the macroscale SERS substrate preparation. The wet-chemistry synthesized AuMs were then immobilized on the grating surface and the produced structure allows SERS measurements with a portable Raman spectrophotometer. The prepared structures were checked using the AFM, UV-Vis, and Raman spectroscopy techniques. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 |
_tPhysical Chemistry Chemical Physics _d1999- |
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| 463 |
_tVol. 19, iss. 22 _v[P. 14761-14769] _d2017 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aкомбинационное рассеяние | |
| 610 | 1 | _aспектроскопия | |
| 610 | 1 | _aнаночастицы | |
| 701 | 1 |
_aKalachyova _bE. _cchemical engineer _cassistant of Tomsk Polytechnic University _f1987- _gEvgeniya _2stltpush _3(RuTPU)RU\TPU\pers\39642 |
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| 701 | 1 |
_aMares _bD. _gDavid |
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| 701 | 1 |
_aJerabek _bV. _gVitezslav |
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| 701 | 1 |
_aUlbrich _bP. _gPavel |
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| 701 | 1 |
_aLapcak _bL. _gLadislav |
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| 701 | 1 |
_aSvorcik _bV. _gVaclav |
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| 701 | 1 |
_aLyutakov _bO. _cchemist-technologist _cAssociate Scientist of Tomsk Polytechnic University _f1982- _gOleksy _2stltpush _3(RuTPU)RU\TPU\pers\36875 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bИнститут природных ресурсов (ИПР) _bКафедра технологии органических веществ и полимерных материалов (ТОВПМ) _h6832 _2stltpush _3(RuTPU)RU\TPU\col\18659 |
| 801 | 2 |
_aRU _b63413507 _c20171213 _gRCR |
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| 856 | 4 | _uhttp://dx.doi.org/10.1039/C7CP01828B | |
| 942 | _cCF | ||