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102 _aPL
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181 0 _ai
182 0 _ab
200 1 _aNanoaluminium: Is There any Relationship betweenParticle Size, Non-isothermal Oxidation Data andBallistics?
_fA. A. Gromov, U. Teipel
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: p. 515-519 (60 tit.)]
330 _aThis article focuses on data analyses and comparisons for aluminium nanopowders (or nanoaluminium, nAl) reactions under slow (0.5-20.0 K/min, using DTA/DSC/TGA) and fast (>10000 K/min, combustion in solid propellant formulations) non-isothermal oxidation. Particle sizes were defined through the BET method. Active Al content was related with the averaged reactivity parameters, taken from published DTA/DSC/TGA data. The specific oxidation onset temperature for nAl was poorly correlated with the BET particle size under the conditions investigated. Furthermore, the BET particle size exhibited no correlation with the observed ballistic response (burning rate) at 3.0 MPa. A logarithmic correlation y = 17.484 ln(x) - 5813, with R² = 0.73, was found between nAl particle size and its aluminium content. A calibration equation for the oxidation onset temperature as a function of nAl particle size was determined as y = −0.0071x2 + 3.3173x + 479.32, with R² = 0.75. Specific features of the nAl (metallic aluminum content in nAl and the oxidation onset temperature) can be predicted based on the measured powder parameters (such as BET particle size).
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tCentral European Journal of Energetic Materials
463 _tVol. 14, iss. 3
_v[P. 501–519]
_d2017
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _acombustion
610 1 _athermal analysis
610 1 _aoxidation
610 1 _ananoaluminium
610 1 _aгорение
610 1 _aтермический анализ
610 1 _aокисление
610 1 _aнаноалюминий
700 1 _aGromov
_bA. A.
_cChemical Engineer
_cProfessor of Tomsk Polytechnic University, Doctor of technical sciences
_f1975-
_gAleksandr Aleksandrovich
_2stltpush
_3(RuTPU)RU\TPU\pers\33059
701 1 _aTeipel
_bU.
_gUlrich
712 0 2 _aНациональный исследовательский Томский политехнический университет (ТПУ)
_bЭнергетический институт (ЭНИН)
_bКафедра атомных и тепловых электростанций (АТЭС)
_h118
_2stltpush
_3(RuTPU)RU\TPU\col\18683
801 2 _aRU
_b63413507
_c20171214
_gRCR
856 4 _uhttps://dx.doi.org/10.22211/cejem/73825
942 _cCF