| 000 | 02930nlm1a2200409 4500 | ||
|---|---|---|---|
| 001 | 656858 | ||
| 005 | 20231030041447.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\23338 | ||
| 090 | _a656858 | ||
| 100 | _a20171215a2017 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_a1 Zn-doped ZIF-67 as catalyst for the CO2 fixation into cyclic carbonates _fA. Zanon [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: 81 tit.] | ||
| 330 | _aA newly Zn-doped ZIF-67 has been synthesized in water at room temperature for the first time without the aid of any organic solvent. The textural and physical properties of the material were analyzed by X-ray diffraction (XRD), thermogravimetric analysis (TGA), N2 adsorption-desorption, scanning electron microscopy (SEM) and ICP-AES. The catalyst showed quantitative conversions and selectivity for the synthesis of cyclic carbonates starting from epoxides and carbon dioxide. Compared with different reported MOFs as heterogeneous catalysts used for the cycloaddition of carbon dioxide to epoxides, this catalyst outperforms all the reported ones till now. The coupling reaction was studied at different pressures and temperatures applying different epoxide substrates. Additionally, no co-catalyst and solvent were required to obtain excellent conversions. The heterogeneous nature of the catalyst was maintained at least up to four catalytic cycles with a slight loss of activity. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tJournal of CO2 Utilization | ||
| 463 |
_tVol. 20 _v[P. 282-291] _d2017 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aкарбонаты | |
| 610 | 1 | _aэпихлоргидрит | |
| 610 | 1 | _aуглекислый газ | |
| 610 | 1 | _aэпоксиды | |
| 610 | 1 | _aцеолиты | |
| 701 | 1 |
_aZanon _bA. _gAdriano |
|
| 701 | 1 |
_aChaemchuen _bS. _cchemist-technologist _cresearcher at Tomsk Polytechnic University _f1984- _gSomboon _2stltpush _3(RuTPU)RU\TPU\pers\42620 |
|
| 701 | 1 |
_aMousavi _bB. _gBibimaryam |
|
| 701 | 1 |
_aVerpoort _bF. V. K. _cchemist-technologist _cProfessor of Tomsk Polytechnic University, doctor of chemical Sciences _f1963- _gFrensis Valter Kornelius _2stltpush _3(RuTPU)RU\TPU\pers\35059 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bИнститут природных ресурсов (ИПР) _bКафедра технологии органических веществ и полимерных материалов (ТОВПМ) _h6832 _2stltpush _3(RuTPU)RU\TPU\col\18659 |
| 801 | 2 |
_aRU _b63413507 _c20190426 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.1016/j.jcou.2017.05.026 | |
| 942 | _cCF | ||