| 000 | 02525nlm1a2200469 4500 | ||
|---|---|---|---|
| 001 | 658228 | ||
| 005 | 20231030041543.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\25552 | ||
| 035 | _aRU\TPU\network\16764 | ||
| 090 | _a658228 | ||
| 100 | _a20180705a2018 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aCH | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aSynthesis and Characterization of Barium Hexafluoridoosmates _fS. I. Ivlev [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: 52 tit.] | ||
| 330 | _aTwo barium hexafluoridoosmates, Ba(OsF6)2 and BaOsF6, were synthesized and were characterized for the first time using X-ray powder and single crystal diffraction, IR spectroscopy, as well as NMR spectroscopy in anhydrous hydrogen fluoride. Ba(OsF6)2 crystallizes in the space group type P21/c with the cell parameters a = 6.4599(4), b = 10.7931(8), c = 14.7476(10) Å, β = 115.195(5)°, V = 930.42(12) Å3, Z = 4 at 293 K. BaOsF6crystallizes in the space group type R 3¯ with the cell parameters a = 7.3286(10), c = 7.2658(15) Å, V = 337.95(12) Å3, Z = 3 at 100 K. Additionally, we have obtained the compounds Ba(OsF6)2∙3BrF3, Ba(OsF6)2∙HF, Ba(OsF6)2∙6H2O from the respective solvents, and Ba(OsF6)2. | ||
| 461 | _tCrystals | ||
| 463 |
_tVol. 8, iss. 1 _v[11, 10 p.] _d2018 |
||
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aосмий | |
| 610 | 1 | _aфториды | |
| 610 | 1 | _aтрифторид брома | |
| 610 | 1 | _aкристаллические структуры | |
| 610 | 1 | _aosmium | |
| 610 | 1 | _afluorides | |
| 610 | 1 | _abromine trifluoride | |
| 610 | 1 | _acrystal structure | |
| 701 | 1 |
_aIvlev _bS. I. _gSergey Ivanovich |
|
| 701 | 1 |
_aKarttunen _bA. J. _gAntti |
|
| 701 | 1 |
_aBuchner _bM. R. _gMagnus |
|
| 701 | 1 |
_aOstvald _bR. V. _cChemical Engineer _cAssociate Professor of Tomsk Polytechnic University, Candidate of chemical sciences _f1980- _gRoman Vyacheslavovich _2stltpush _3(RuTPU)RU\TPU\pers\31221 |
|
| 701 | 1 |
_aKraus _bF. _gFlorian |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИнженерная школа ядерных технологий _bОтделение ядерно-топливного цикла _h7864 _2stltpush _3(RuTPU)RU\TPU\col\23554 |
| 801 | 2 |
_aRU _b63413507 _c20180705 _gRCR |
|
| 856 | 4 | 0 | _uhttps://doi.org/10.3390/cryst8010011 |
| 942 | _cCF | ||