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100 _a20181022a2018 k y0engy50 ba
101 0 _aeng
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aInfluence of deposition conditions on mechanical properties of a-C:H:SiOx films prepared by plasma-assisted chemical vapor deposition method
_fA. S. Grenaderov [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 37 tit.]
330 _aA series of a-C:H:SiOx films was deposited on polished silicon and glass substrates by plasma-assisted chemical vapor deposition combined with pulsed bipolar substrate bias from mixtures of argon and polyphenylmethylsiloxane vapors. Different Ar pressures and substrate bias voltages were applied for the synthesis of a-C:H:SiOx films having different mechanical properties. Detailed characterization of the mechanical properties of a-C:H:SiOx films was made using the nanoindentation. Hardness and elastic modulus were used for the evaluation of the endurance capability (H/E) and resistance to plastic deformation (H3/E2). The structural properties of the deposited films were analyzed by Fourier transform infrared spectroscopy (FTIR) and Raman spectroscopy. It was shown that the Ar pressure and substrate bias variation can change the film properties and the growth rate and these changes are not linear. So, depending upon application, deposition conditions are to be optimized. In all of the examined coatings, increase of Ar pressure and amplitude of negative pulse of substrate bias lead to improvement in mechanical properties. According to the results of FTIR and Raman spectroscopy; this improvement is due to an increase in the sp3 bonded carbon content and decrease of hydrogen content in the films.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tSurface and Coatings Technology
463 _tVol. 349
_v[P. 547-555]
_d2018
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _aa-C:H:SiOx films
610 1 _aPlasma CVD
610 1 _aспектроскопия
610 1 _aсмещение
_aFTIR spectroscopy
610 1 _aсмещение
610 1 _aSubstrate bias
701 1 _aGrenaderov
_bA. S.
_gAleksandr Sergeevich
701 1 _aSoloviev
_bA. A.
_cspecialist in the field of hydrogen energy
_cAssociate Professor of Tomsk Polytechnic University, Candidate of technical sciences
_f1977-
_gAndrey Aleksandrovich
_2stltpush
_3(RuTPU)RU\TPU\pers\30863
701 1 _aOskomov
_bK. V.
_gKonstantin Vladimirovich
701 1 _aSypchenko
_bV. S.
_cphysicist
_cAssociate Scientist of Tomsk Polytechnic University, assistant
_f1987-
_gVladimir Sergeevich
_2stltpush
_3(RuTPU)RU\TPU\pers\33791
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИнженерная школа ядерных технологий
_bНаучно-образовательный центр Б. П. Вейнберга
_h7866
_2stltpush
_3(RuTPU)RU\TPU\col\23561
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИнженерная школа ядерных технологий
_bОтделение экспериментальной физики
_h7865
_2stltpush
_3(RuTPU)RU\TPU\col\23549
801 2 _aRU
_b63413507
_c20181022
_gRCR
856 4 _uhttps://doi.org/10.1016/j.surfcoat.2018.06.019
942 _cCF