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|---|---|---|---|
| 001 | 658695 | ||
| 005 | 20231030041602.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\26672 | ||
| 090 | _a658695 | ||
| 100 | _a20181106a2018 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aStudy of electrooxidation of binary electrolytic deposit palladium–bismuth deposited on graphite electrode surface _fZh. K. Sabitova, Yu. A. Oskina, N. A. Kolpakova |
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| 203 |
_aText _celectronic |
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| 300 | _aTitle screen | ||
| 320 | _a[References: 31 tit.] | ||
| 330 | _aThe phase structure of palladium–bismuth binary electrolytic deposit was studied. The electrodeposition of deposit components on the surface of a graphite electrode (GE) was carried out in situ. On current–voltage curves, the peak of bismuth electrooxidation, the peak of palladium electrooxidation and an additional peak at 0.15 V vs. Ag/AgCl are observed. The peak current at 0.15 V depends both on the concentration of palladium(II) ions and on that of bismuth(III) ions. The thermodynamic theory of alloys in the approximation of the theory of regular solutions was used for calculations. The mixing heat of the binary alloy components and the equilibrium potential of bismuth in the bismuth–palladium alloy are calculated. The calculated equilibrium potential of bismuth in an alloy with palladium is 0.12 V vs. Ag/AgCl which corresponds to the Bi2Pd intermetallic compound (IMC). Investigation of the surface of a GE with a palladium–bismuth deposit with use of scanning electron microscope showed that the electrolytic deposit contains bismuth, palladium and the Bi2Pd IMC. Peak at the potential of plus 0.15 V vs. Ag/AgCl is due to selective bismuth electrooxidation from the Bi2Pd IMC. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 |
_tJournal of Solid State Electrochemistry _oScientific Journal |
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| 463 |
_tVol. 22, iss. 12 _v[7 p.] _d2018 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aмодифицированные электроды | |
| 610 | 1 | _aместорождения | |
| 610 | 1 | _aсмешивание | |
| 610 | 1 | _aкомпоненты | |
| 610 | 1 | _aвольтамперометрия | |
| 700 | 1 |
_aSabitova _bZh. K. _gZhamilya Korganbekovna |
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| 701 | 1 |
_aOskina _bYu. A. _cChemical Engineer _cEngineer-researcher of Tomsk Polytechnic University _f1990- _gYuliya Aleksandrovna _2stltpush _3(RuTPU)RU\TPU\pers\33252 |
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| 701 | 1 |
_aKolpakova _bN. A. _cMaiden Name Polukarova _crussian chemist _f1942- _gNina Alexandrovna _2stltpush _3(RuTPU)RU\TPU\pers\28201 |
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| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИнженерная школа природных ресурсов _bОтделение химической инженерии _h8085 _2stltpush _3(RuTPU)RU\TPU\col\23513 |
| 801 | 2 |
_aRU _b63413507 _c20181106 _gRCR |
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| 856 | 4 | 0 | _uhttps://doi.org/10.1007/s10008-018-4084-y |
| 942 | _cCF | ||