| 000 | 03419nla2a2200445 4500 | ||
|---|---|---|---|
| 001 | 659136 | ||
| 005 | 20231030041618.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\27583 | ||
| 035 | _aRU\TPU\network\27582 | ||
| 090 | _a659136 | ||
| 100 | _a20190122a2018 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 105 | _ay z 100zy | ||
| 135 | _adrgn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aAnalytical Pyrolysis of Insoluble Products Obtained by Thermolysis of Resins and Asphaltenes of the Oil from the Usinskoye Oil Field _fV. R. Antipenko [et al.] |
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| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: 15 tit.] | ||
| 330 | _aPresented are the results on the study of insoluble products obtained at autoclave thermolysis of resins and asphaltenes of the oil from the Usinskoye oil field in an argon atmosphere at 160-650°С. A high yielded chloroforminsoluble thermolysis product obtained from the resins of heavy high-sulfur oil at 250°C significantly differs from products obtained from resins and asphaltenes at 450 and 650°C but according to the results of Rock Eval and 'on-line' flash pyrolysis (600°C, 20 s), and elemental analysis it is similar to 'asphaltene-like' substances. Their formation is probably due to the cleavage at 250°C of the most labile S-S or C-S bonds in the resin molecules followed by generation and recombination of macroradicals. The thermal destruction of these substances at higher temperatures (450 and 650°C) is accompanied by the formation of more carbonized coke-like products. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | 0 |
_0(RuTPU)RU\TPU\network\4816 _tAIP Conference Proceedings |
|
| 463 | 0 |
_0(RuTPU)RU\TPU\network\27575 _tVol. 2051 : Advanced Materials with Hierarchical Structure for New Technologies and Reliable Structures 2018 (AMHS’18) _oProceedings of the International conference, 1–5 October 2018, Tomsk, Russia _fNational Research Tomsk Polytechnic University (TPU); eds. V. E. Panin, S. G. Psakhie, V. M. Fomin _v[020019, 4 p.] _d2018 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aпиролиз | |
| 610 | 1 | _aнерастворимые продукты | |
| 610 | 1 | _aтермолиз | |
| 610 | 1 | _aсмолы | |
| 610 | 1 | _aасфальтены | |
| 610 | 1 | _aУсинское месторождение | |
| 701 | 1 |
_aAntipenko _bV. R. _gVladimir |
|
| 701 | 1 |
_aGrinko _bA. A. _cgeochemist _cresearch engineer of Tomsk Polytechnic University, candidate of chemical sciences _f1986- _gAndrey Alekseevich _2stltpush _3(RuTPU)RU\TPU\pers\36888 |
|
| 701 | 1 |
_aGolovko _bA. K. _gAnatoly |
|
| 701 | 1 |
_aMelenevskiy _bV. N. _gVasily |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет (ТПУ) _bИнститут природных ресурсов (ИПР) _bКафедра геологии и разведки полезных ископаемых (ГРПИ) _bМеждународная научно-образовательная лаборатория изучения углерода арктических морей (МНОЛ ИУАМ) _h7398 _2stltpush _3(RuTPU)RU\TPU\col\20711 |
| 801 | 2 |
_aRU _b63413507 _c20190122 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.1063/1.5083262 | |
| 942 | _cCF | ||