| 000 | 02930nlm1a2200433 4500 | ||
|---|---|---|---|
| 001 | 659364 | ||
| 005 | 20231030041626.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\27914 | ||
| 090 | _a659364 | ||
| 100 | _a20190214a2019 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aNL | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aAmorphization of Degussa nanosized TiO2 caused by its modification _fE. V. Khramov [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: 63 tit.] | ||
| 330 | _aInfluence of modification with metals Au and Ag, oxides of Fe, Mg and Ce and their combinations on amorphization of widely used commercial nanosized TiO2 (Degussa P25) was studied with SR-XRD and EXAFS methods. These systems were chosen taking into account their potential on catalytic properties for biomass to biodiesel transformation, as it was shown in model reaction of liquid phase n-octanol oxidation as well as low-temperature CO oxidation for “cold start” of the neutralizers of car exhaust gases. Instability of rutile, the most stable TiO2 phase, in the presence of the additives was found. Application of EXAFS method, rarely used for crystalline structure transfer studies, led to elucidation of this apparent effect, which was explained by higher level of amorphization of rutile than anatase. Literature data indicate that bulky TiO2 doping leads to either increase of rutile/anatase ratio complete inhibition of anatase to rutile transformation. Dissimilar phase composition changes, revealed in this work for modified nanodispersed TiO2, was attributed to size effect. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tFuel | ||
| 463 |
_tVol. 234 _v[P. 312-317] _d2018 |
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| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aаморфизация | |
| 610 | 1 | _aдифракция | |
| 610 | 1 | _aрентгеновские лучи | |
| 610 | 1 | _aсинхротронное излучение | |
| 701 | 1 |
_aKhramov _bE. V. _gEvgeny Vladimirovich |
|
| 701 | 1 |
_aKotolevich _bY. S. |
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| 701 | 1 |
_aRamos _bJ. C. |
|
| 701 | 1 |
_aPestryakov _bA. N. _cChemist _cProfessor of Tomsk Polytechnic University, Doctor of Chemical Science _f1963- _gAleksey Nikolaevich _2stltpush _3(RuTPU)RU\TPU\pers\30471 |
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| 701 | 1 |
_aZubavichus _bY. V. _gYan Vitautasovich |
|
| 701 | 1 |
_aBogdanchikova _bN. |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИсследовательская школа химических и биомедицинских технологий (ИШХБМТ) _c(2017- ) _h8120 _2stltpush _3(RuTPU)RU\TPU\col\23537 |
| 801 | 2 |
_aRU _b63413507 _c20190214 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.1016/j.fuel.2018.06.127 | |
| 942 | _cCF | ||