| 000 | 03381nlm1a2200421 4500 | ||
|---|---|---|---|
| 001 | 659407 | ||
| 005 | 20231030041628.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\27963 | ||
| 090 | _a659407 | ||
| 100 | _a20190215a2018 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aSpray drying of zeolitic imidazolate frameworks: investigation of crystal formation and properties _fS. Chaemchuen [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 330 | _aHigh-quality zeolite imidazole frameworks (ZIF-8, ZIF-67, and bimetallic Zn/Co-ZIF) were synthesized using the spray-drying technique and the mechanism of crystal growth during the whole process is discussed. It is also demonstrated that the crystallization mechanism for N-donor containing ditopic imidazolate (IM) ligands forming ZIF structures is divergent from MOF formation applying carboxylate ligands, and their formation using the spray dry method occurs via a unique mechanism. An intermediate amorphous phase was obtained after spray drying the feed solution, and the crystallographic ZIF structure was obtained during immersion in a solvent. Several characterization techniques, such as FTIR, XRD, SEM, porosity analysis, elemental analysis etc., were applied to examine the characteristic properties of materials, including, intermediate compounds and final products. The results proved that the spray drying procedure is a facile, continuous and effective synthetic route to produce MOFs (ZIFs) in higher quantities with high-quality properties such as high porosity, a large surface area, more active catalyst sites, etc. applying a minimum amount of time and energy which is unusual in common synthesis methods of MOFs. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tCrystEngComm | ||
| 463 |
_tVol. 20, iss. 25 _v[С. 3601-3608] _d2018 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aраспылительная сушка | |
| 610 | 1 | _aцеолитные системы | |
| 610 | 1 | _aкристаллообразование | |
| 701 | 0 |
_aChaemchuen _bS. _cchemist-technologist _cresearcher at Tomsk Polytechnic University _f1984- _gSomboon _2stltpush _3(RuTPU)RU\TPU\pers\42620 |
|
| 701 | 0 | _aZhou Kui | |
| 701 | 1 |
_aMousavi _bB. _gBibimaryam |
|
| 701 | 1 |
_aGhadamyari _bM. _gMarzie |
|
| 701 | 1 |
_aHeynderickx _bPh. M. _gPhilippe |
|
| 701 | 1 |
_aZhuiykov _bS. _gSerge |
|
| 701 | 1 |
_aYusubov _bM. S. _cchemist _cProfessor of Tomsk Polytechnic University, Doctor of chemical sciences _f1961- _gMekhman Suleiman-Ogly (Suleimanovich) _2stltpush _3(RuTPU)RU\TPU\pers\31833 |
|
| 701 | 1 |
_aVerpoort _bF. V. K. _cChemical Engineer _cProfessor of Tomsk Polytechnic University, doctor of chemical Sciences _f1963- _gFrensis Valter Kornelius _2stltpush _3(RuTPU)RU\TPU\pers\35059 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИсследовательская школа химических и биомедицинских технологий (ИШХБМТ) _c(2017- ) _h8120 _2stltpush _3(RuTPU)RU\TPU\col\23537 |
| 801 | 2 |
_aRU _b63413507 _c20190215 _gRCR |
|
| 856 | 4 | _uhttp://dx.doi.org/10.1039/C8CE00392K | |
| 942 | _cCF | ||