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100 _a20190221a2018 k y0engy50 ba
101 0 _aeng
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aVerdazyl Radical Building Blocks: Synthesis, Structure, and Sonogashira Cross-Coupling Reactions
_fP. V. Petunin [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 37 tit.]
330 _aA general and effective method for the synthesis of 3?phenylveradzyl radicals bearing a variety of iodophenyl substituents has been developed. The synthesized radicals have been characterized by ESR, UV/Vis spectroscopy, and cyclic voltammetry. Structures of biphenyl?substituted radicals have been solved by X?ray crystal structure analysis. The synthesized iodoverdazyls are applicable in the Sonogashira coupling reaction for the preparation of a wide range of ethynyl derivatives. Both N?2 and C?6 substituents were functionalized through Sonogashira coupling.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tEuropean Journal of Organic Chemistry
463 _tVol. 2018, iss. 34
_v[P. 4802-4811]
_d2018
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _averdazyl radicals
610 1 _anitrogen heterocycles
610 1 _across‐coupling
610 1 _adensity functional calculations
610 1 _aвердазильные радикалы
610 1 _aгетероциклы
610 1 _aкросс-средства
610 1 _aрасчеты
701 1 _aPetunin
_bP. V.
_cchemist
_cEngineer of Tomsk Polytechnic University
_f1982-
_gPavel Vasilievich
_2stltpush
_3(RuTPU)RU\TPU\pers\36904
701 1 _aMartynko
_bE. A.
_gEkaterina Andreevna
701 1 _aTrusova
_bM. E.
_corganic chemist
_cAssociate professor of Tomsk Polytechnic University, Candidate of chemical sciences
_f1982-
_gMarina Evgenievna
_2stltpush
_3(RuTPU)RU\TPU\pers\31823
701 1 _aKazantsev
_bM. S.
_gMaksim Sergeevich
701 1 _aRybalova
_bT. V.
_gTatjyana Valerjevna
701 1 _aValiev
_bR. R.
_cchemist
_cAssistant of Tomsk Polytechnic University
_f1983-
_gRashid Rinatovich
_2stltpush
_3(RuTPU)RU\TPU\pers\34114
701 1 _aUvarov
_bM. N.
_gMikhail Nikolaevich
701 1 _aMostovich
_bE. A.
_gEvgeny Alekseevich
701 1 _aPostnikov
_bP. S.
_corganic chemist
_cSenior Lecturer of Tomsk Polytechnic University, Candidate of chemical sciences
_f1984-
_gPavel Sergeevich
_2stltpush
_3(RuTPU)RU\TPU\pers\31287
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИсследовательская школа химических и биомедицинских технологий (ИШХБМТ)
_c(2017- )
_h8120
_2stltpush
_3(RuTPU)RU\TPU\col\23537
801 2 _aRU
_b63413507
_c20190221
_gRCR
856 4 _uhttps://doi.org/10.1002/ejoc.201701783
942 _cCF