| 000 | 02880nlm1a2200481 4500 | ||
|---|---|---|---|
| 001 | 659710 | ||
| 005 | 20231030041638.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\28472 | ||
| 090 | _a659710 | ||
| 100 | _a20190325a2018 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aPreparation, structure, and reactivity of bicyclic benziodazole: a new hypervalent iodine heterocycle _fA. Yoshimura, M. T. Shea , C. L. Makitalo [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: 38 tit.] | ||
| 330 | _aA new bicyclic organohypervalent iodine heterocycle derivative of benziodazole was prepared by oxidation of 2-iodo-N,N’-diisopropylisophthalamide with m-chloroperoxybenzoic acid under mild conditions. Single crystal X-ray crystallography of this compound revealed a five-membered bis-heterocyclic structure with two covalent bonds between the iodine atom and the nitrogen atoms. This novel benziodazole is a very stable compound with good solubility in common organic solvents. This compound can be used as an efficient reagent for oxidatively assisted coupling of carboxylic acids with alcohols or amines to afford the corresponding esters or amides in moderate yields. | ||
| 461 | _tBeilstein Journal of Organic Chemistry | ||
| 463 |
_tVol. 14 _v[P. 1016-1020] _d2018 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aгипервалентный йод | |
| 610 | 1 | _aйод | |
| 610 | 1 | _ahypervalent iodine | |
| 610 | 1 | _abenziodazole | |
| 610 | 1 | _abiheterocycles | |
| 610 | 1 | _ahypervalent iodine | |
| 610 | 1 | _aiodine | |
| 610 | 1 | _aoxidatively assisted esterification | |
| 701 | 1 |
_aYoshimura _bA. _cchemical engineer _cProfessor of Tomsk Polytechnic University _f1981- _gAkira _2stltpush _3(RuTPU)RU\TPU\pers\39852 |
|
| 701 | 1 |
_aShea _bM. T. _gMichael T. |
|
| 701 | 1 |
_aMakitalo _bC. L. _gCody L. |
|
| 701 | 1 |
_aJarvi _bM. E. _gMelissa E. |
|
| 701 | 1 |
_aRohde _bG. T. _gGregory T. |
|
| 701 | 1 |
_aSaito _bA. _gAkio |
|
| 701 | 1 |
_aYusubov _bM. S. _cchemist _cProfessor of Tomsk Polytechnic University, Doctor of chemical sciences _f1961- _gMekhman Suleiman-Ogly (Suleimanovich) _2stltpush _3(RuTPU)RU\TPU\pers\31833 |
|
| 701 | 1 |
_aZhdankin _bV. V. _cхимик _cProfessor of Tomsk Polytechnic University, Doctor of chemical sciences _f1956- _gViktor Vladimirovich _2stltpush _3(RuTPU)RU\TPU\pers\35758 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИсследовательская школа химических и биомедицинских технологий (ИШХБМТ) _c(2017- ) _h8120 _2stltpush _3(RuTPU)RU\TPU\col\23537 |
| 801 | 2 |
_aRU _b63413507 _c20200310 _gRCR |
|
| 856 | 4 | _uhttp://dx.doi.org/10.3762/bjoc.14.87 | |
| 942 | _cCF | ||