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100 | _a20190412a2019 k y0engy50 ba | ||
101 | 0 | _aeng | |
102 | _aUS | ||
135 | _adrnn ---uucaa | ||
181 | 0 | _ai | |
182 | 0 | _ab | |
200 | 1 |
_aReflections on Factors that Affect the Duration and Accuracy of Isopiestic Investigations _fA. G. Tereshchenko |
|
203 |
_aText _celectronic |
||
300 | _aTitle screen | ||
320 | _a[References: 49 tit.] | ||
330 | _aThis review article considers factors that affect the duration and accuracy of isopiestic investigations, analyzes data from published papers, and provides the author’s critical opinion. The interrelation between the mass of the transported water vapor during isothermal distillation and the driving force behind the process for solutions of various concentrations is studied. The significance of the effects of removal of air, agitating in the liquid and gas phases, materials of the isopiestic cups on the duration of the isopiestic process is also analyzed. Attention is paid to the fact that if an initial reagent that contains 0.99 mol fraction main component is used without prior purification, then the accuracy of this isopiestic investigation is questionable even in the second figure of the isopiestic measurement result. | ||
333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
461 | _tJournal of Solution Chemistry | ||
463 |
_tVol. 48, iss. 3 _v[P. 354-366] _d2019 |
||
610 | 1 | _aэлектронный ресурс | |
610 | 1 | _aтруды учёных ТПУ | |
610 | 1 | _aisopiestic method | |
610 | 1 | _arate-limiting step | |
610 | 1 | _aaccuracy of results | |
610 | 1 | _aexperiment duration | |
610 | 1 | _areview | |
610 | 1 | _aизопиестические методы | |
610 | 1 | _aточность | |
610 | 1 | _aрезультаты | |
610 | 1 | _aпродолжительность | |
610 | 1 | _aэксперименты | |
610 | 1 | _aобзор | |
700 | 1 |
_aTereshchenko _bA. G. _cChemical Engineer _cHead of the laboratory of Tomsk Polytechnic University, Candidate of technical science _f1946- _gAnatoly Georgievich _2stltpush _3(RuTPU)RU\TPU\pers\31487 |
|
712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИнженерная школа новых производственных технологий _bНаучно-производственная лаборатория "Чистая вода" _h7886 _2stltpush _3(RuTPU)RU\TPU\col\23657 |
801 | 2 |
_aRU _b63413507 _c20200827 _gRCR |
|
856 | 4 | _uhttps://doi.org/10.1007/s10953-019-00849-3 | |
942 | _cCF |