000 02822nlm1a2200457 4500
001 659975
005 20231030041648.0
035 _a(RuTPU)RU\TPU\network\28832
090 _a659975
100 _a20190412a2019 k y0engy50 ba
101 0 _aeng
102 _aUS
135 _adrnn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aReflections on Factors that Affect the Duration and Accuracy of Isopiestic Investigations
_fA. G. Tereshchenko
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 49 tit.]
330 _aThis review article considers factors that affect the duration and accuracy of isopiestic investigations, analyzes data from published papers, and provides the author’s critical opinion. The interrelation between the mass of the transported water vapor during isothermal distillation and the driving force behind the process for solutions of various concentrations is studied. The significance of the effects of removal of air, agitating in the liquid and gas phases, materials of the isopiestic cups on the duration of the isopiestic process is also analyzed. Attention is paid to the fact that if an initial reagent that contains 0.99 mol fraction main component is used without prior purification, then the accuracy of this isopiestic investigation is questionable even in the second figure of the isopiestic measurement result.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tJournal of Solution Chemistry
463 _tVol. 48, iss. 3
_v[P. 354-366]
_d2019
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _aisopiestic method
610 1 _arate-limiting step
610 1 _aaccuracy of results
610 1 _aexperiment duration
610 1 _areview
610 1 _aизопиестические методы
610 1 _aточность
610 1 _aрезультаты
610 1 _aпродолжительность
610 1 _aэксперименты
610 1 _aобзор
700 1 _aTereshchenko
_bA. G.
_cChemical Engineer
_cHead of the laboratory of Tomsk Polytechnic University, Candidate of technical science
_f1946-
_gAnatoly Georgievich
_2stltpush
_3(RuTPU)RU\TPU\pers\31487
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИнженерная школа новых производственных технологий
_bНаучно-производственная лаборатория "Чистая вода"
_h7886
_2stltpush
_3(RuTPU)RU\TPU\col\23657
801 2 _aRU
_b63413507
_c20200827
_gRCR
856 4 _uhttps://doi.org/10.1007/s10953-019-00849-3
942 _cCF