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035 _a(RuTPU)RU\TPU\network\29043
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100 _a20190424a2018 k y0engy50 ba
101 0 _aeng
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aHigh resolution analysis of the FTIR spectra of trifluoroamine NF3
_fI. B. Bolotova [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: p. 101-102 (67 tit.)]
330 _aWe report high resolution Fourier Transform Infrared (FTIR) spectra of nitrogen trifluoride (trifluoroamine, NF3) measured with the Zürich Bruker prototype spectrometer (ZP 2001) and the SLS THz/FTIR setup (2009 prototype) in the range 20-3000 cm-1 at temperatures between 80 and 120 K using a collisional cooling cell designed with White cell multipath reflection optics and at room temperature (296 K). Except in the far-infrared with instrument limited resolution (Δν̃FWHM = 0.0008 cm-1) many of the spectra are nearly Doppler limited. Rovibrational transitions were assigned to 13 different vibrational bands and were used then in the fitting procedure. We re-investigated the bands 2ν4,ν1,ν2+ν4,ν1+ν4, 2ν3 and ν1+ν3, which had been studied before, and we have analyzed the ν2+ν3, 2ν1,ν1+ν2+ν4,ν1+ν2+ν3,ν2+2ν3,3ν3,ν1+2ν3 bands for the first time. All our analyses refer to the isotopomer 14NF3.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tJournal of Molecular Spectroscopy
463 _tVol. 348
_v[P. 87-102]
_d2018
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _atrifluoroamine
610 1 _aatmospheric trace gases
610 1 _agreenhouse effect
610 1 _ahigh resolution infrared spectroscopy Overtones
610 1 _acombination bands rovibrational analysis
610 1 _aатмосферные газы
610 1 _aпарниковый эффект
610 1 _aинфракрасная спектрофотометрия
701 1 _aBolotova
_bI. B.
_cphysicist
_cTechnician of Tomsk Polytechnic University
_f1989-
_gIrina Batorovna
_2stltpush
_3(RuTPU)RU\TPU\pers\34081
701 1 _aUlenekov (Ulenikov)
_bO. N.
_cphysicist
_cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences
_f1949-
_gOleg Nikolaevich
_2stltpush
_3(RuTPU)RU\TPU\pers\34331
701 1 _aBekhtereva
_bE. S.
_cphysicist
_cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences
_f1974-
_gElena Sergeevna
_2stltpush
_3(RuTPU)RU\TPU\pers\34450
701 1 _aAlbert
_bS.
_gSieghard
701 1 _aHollenstein
_bH. A.
_gHans
701 1 _aQuack
_bM.
_gMartin
701 1 _aPeter
_bT.
701 1 _aSeyfang
_bG.
_gGeorg
701 1 _aWokaun
_bA.
_gAlexander
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИсследовательская школа физики высокоэнергетических процессов
_c(2017- )
_h8118
_2stltpush
_3(RuTPU)RU\TPU\col\23551
801 2 _aRU
_b63413507
_c20190424
_gRCR
856 4 _uhttps://doi.org/10.1016/j.jms.2018.04.004
942 _cCF