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035 _a(RuTPU)RU\TPU\network\29080
090 _a660130
100 _a20190426a2018 k y0engy50 ba
101 0 _aeng
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aSynthesis of β-oxopropylcarbamates in a recyclable AgBr/ionic liquid catalytic system: An efficient assembly of CO2 under ambient pressure
_fSong Dandan [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 22 tit.]
330 _aA green and recyclable catalytic system based on AgBr and an ionic liquid (IL) was developed for the three-component coupling reaction of propargylic alcohols, secondary amines and carbon dioxide (CO2). A series of target carbamates, especially those generated from challenging substrates, could be obtained smoothly at atmospheric CO2 pressure in a straightforward one-pot process. Moreover, the catalyst loading reached the lowermost level ever reported. Particularly, this catalytic system exhibited robust constancy and could be reused at least 5 times with retention of high catalytic activity. It is worth noting that this is the first catalytic system which could be recycled successfully for this reaction.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tJournal of CO2 Utilization
463 _tVol. 27
_v[P. 217-222]
_d2018
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _aβ-Oxopropylcarbamates
610 1 _aionic liquids
610 1 _athree-component coupling reaction
610 1 _asilver
610 1 _arecyclability
610 1 _aионные жидкости
610 1 _aреакции
610 1 _aсеребро
610 1 _aвторичная переработка
701 0 _aSong Dandan
701 0 _aLia Di
701 0 _aXiao Xuan
701 0 _aCheng Chen
701 0 _aChaemchuen
_bS.
_cchemist-technologist
_cresearcher at Tomsk Polytechnic University
_f1984-
_gSomboon
_2stltpush
_3(RuTPU)RU\TPU\pers\42620
701 0 _aYuan Ye
701 1 _aVerpoort
_bF. V. K.
_cchemist-technologist
_cProfessor of Tomsk Polytechnic University, doctor of chemical Sciences
_f1963-
_gFrensis Valter Kornelius
_2stltpush
_3(RuTPU)RU\TPU\pers\35059
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИсследовательская школа химических и биомедицинских технологий (ИШХБМТ)
_c(2017- )
_h8120
_2stltpush
_3(RuTPU)RU\TPU\col\23537
801 2 _aRU
_b63413507
_c20191125
_gRCR
856 4 _uhttps://doi.org/10.1016/j.jcou.2018.07.021
942 _cCF