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001 660136
005 20231030041655.0
035 _a(RuTPU)RU\TPU\network\29086
035 _aRU\TPU\network\28572
090 _a660136
100 _a20190426a2018 k y0engy50 ba
101 0 _aeng
102 _aUS
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aParameters of Iron and Aluminum Nano- and Micropowder Activity upon Oxidation in Air under Microwave Irradiation
_fA. V. Mostovshchikov [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 21 tit.]
330 _aIron nanopowders and iron and aluminum micropowders exposed to microwave radiation with a frequency of 9.4 GHz and a power density of 80 W/cm2 at a pulse repetition rate of 400 Hz have been investigated. According to the results of differential thermal analysis, the microwave radiation caused nonmonotonic changes in the thermal properties of the A1 and Fe powders. After irradiation of the iron nanopowder, the temperature of the onset of its oxidation increased from 150.01 to 158.75°C; in the case of the micropowder, the temperature nonmonotonically changed from 150.00 to 275.38°C. The specific heat of oxidation of the Fe nanopowder increased by 17.3% at maximum, while in the Fe micropowder the maximum attained increase was 13%. For the Al micropowder, the maximum increase in the specific heat of oxidation was found to be 59.7%. Microwave irradiation leads to the formation of electron avalanches, which reduce metal ions in their oxides. At the same time, at certain irradiation doses the generated electron flows oxidize the reduced metals, which is reflected in the nonmonotonic variation in the properties of a material. The increase in the specific heat of oxidation is related to the participation of energy-saturated states of the metals in the oxidation processes.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tJournal of Applied Mechanics and Technical Physics
463 _tVol. 63, iss. 9
_v[P. 1223-1227]
_d2018
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _aнанопорошки
610 1 _aжелезо
610 1 _aалюминий
610 1 _aокисление в воздухе
610 1 _aмикроволновое облучение
701 1 _aMostovshchikov
_bA. V.
_cChemist
_cEngineer of Tomsk Polytechnic University
_f1989-
_gAndrey Vladimirovich
_2stltpush
_3(RuTPU)RU\TPU\pers\31091
701 1 _aIlyin
_bA. P.
_cchemist
_cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences
_f1949-
_gAleksandr Petrovich
_2stltpush
_3(RuTPU)RU\TPU\pers\33060
701 1 _aChumerin
_bP. Yu.
_cphysicist
_cSenior researcher of Tomsk Polytechnic University, Doctor of physical and mathematical science
_f1958-
_gPavel Yurievich
_2stltpush
_3(RuTPU)RU\TPU\pers\32716
701 1 _aYushkov
_bY. G.
_celectrophysicist
_cProfessor of Tomsk Polytechnic University, Doctor of technical sciences
_f1937-
_gYuri Georgievich
_2stltpush
_3(RuTPU)RU\TPU\pers\25936
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИнженерная школа ядерных технологий
_bНаучно-исследовательская лаборатория СВЧ-технологии
_h7869
_2stltpush
_3(RuTPU)RU\TPU\col\23457
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bШкола базовой инженерной подготовки
_bОтделение естественных наук
_h8032
_2stltpush
_3(RuTPU)RU\TPU\col\23562
801 2 _aRU
_b63413507
_c20190426
_gRCR
856 4 _uhttps://doi.org/10.1134/S1063784218080133
942 _cCF