| 000 | 03149nlm1a2200397 4500 | ||
|---|---|---|---|
| 001 | 660256 | ||
| 005 | 20231030041659.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\29336 | ||
| 035 | _aRU\TPU\network\14276 | ||
| 090 | _a660256 | ||
| 100 | _a20190516a2019 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aNL | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aSolid-state transformation in porous metal-organic frameworks based on polymorphic-pillared net structure: Generation of tubular shaped MOFs _fChaemchuen Somboon, K. Zhou, M. S. Yusubov [et al.] |
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| 203 |
_aText _celectronic |
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| 300 | _aTitle screen | ||
| 320 | _a[References: 38 tit.] | ||
| 330 | _aA first time report on a solid-state polymorphic transformation of MOF materials [Zn2(bdc)2(dabco)]n (ZnBD) and [Co2(bdc)2(dabco)]n (CoBD) from a pillared kagomй-lattice form (ZnBDkgm or CoBDkgm) to a pillared square-lattice form (ZnBDsql or CoBDsql) at ambient condition is given. Several solvents were applied as a guest-driven molecule to trigger the solid-to-solid transformation while only methanol demonstrated to be able to perform this transformation. The methanol-driven solid-state transformation behavior was observed by using powder X-ray diffraction. The morphology investigated that the rod-like Kagomй form rapidly transformed into a tubular square lattice upon addition of methanol at room temperature. The characteristic porosity reconfirmed the transformation was complete. A transformation mechanism of disconnection-deformation-rebuilding was elucidated based on the experiment. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tMicroporous and Mesoporous Materials | ||
| 463 |
_tVol. 278 _v[P. 99–104] _d2019 |
||
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aэлектронный ресурс | |
| 701 | 0 |
_aChaemchuen Somboon _cchemist-technologist _cresearcher at Tomsk Polytechnic University, Ph.D _f1984- _2stltpush _3(RuTPU)RU\TPU\pers\42620 |
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| 701 | 1 |
_aZhou _bK. _gKui |
|
| 701 | 1 |
_aYusubov _bM. S. _cchemist _cProfessor of Tomsk Polytechnic University, Doctor of chemical sciences _f1961- _gMekhman Suleiman-Ogly (Suleimanovich) _2stltpush _3(RuTPU)RU\TPU\pers\31833 |
|
| 701 | 1 |
_aPostnikov _bP. S. _corganic chemist _cSenior Lecturer of Tomsk Polytechnic University, Candidate of chemical sciences _f1984- _gPavel Sergeevich _2stltpush _3(RuTPU)RU\TPU\pers\31287 |
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| 701 | 1 |
_aKlomkliang _bN. _gNikom |
|
| 701 | 1 |
_aVerpoort _bF. V. K. _cChemical Engineer _cProfessor of Tomsk Polytechnic University, doctor of chemical Sciences _f1963- _gFrensis Valter Kornelius _2stltpush _3(RuTPU)RU\TPU\pers\35059 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИсследовательская школа химических и биомедицинских технологий (ИШХБМТ) _c(2017- ) _h8120 _2stltpush _3(RuTPU)RU\TPU\col\23537 |
| 801 | 2 |
_aRU _b63413507 _c20200904 _gRCR |
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| 856 | 4 | 0 | _uhttps://doi.org/10.1016/j.micromeso.2018.11.023 |
| 942 | _cCF | ||