| 000 | 02710nlm1a2200469 4500 | ||
|---|---|---|---|
| 001 | 660275 | ||
| 005 | 20231030041659.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\29396 | ||
| 035 | _aRU\TPU\network\28047 | ||
| 090 | _a660275 | ||
| 100 | _a20190522a2018 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aHetero Diels–Alder Reaction and Ene Reaction of Acylnitroso Species in situ Generated by Hypoiodite Catalysis _fS. Uraoka, I. Shinohara, H. Shimizu [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 320 | _a[References: 19 tit.] | ||
| 330 | _aAs a first non?metal?catalyzed oxidation for the in situ generation of acylnitroso species, we describe the hypoiodite catalysis using tetra?n?butylammonium iodide as precatalyst with tert?butyl hydroperoxide or hydrogen peroxide as a terminal oxidant. This method can be applied to hetero Diels–Alder (HDA) reactions with dienes and ene reactions with alkenes. Furthermore, the conversions of the representative HDA adduct to nitrone and 2?amino alcohols were demonstrated. Compared with previous metal?catalyzed oxidation methods, this work provides a more efficient and environmentally friendly procedure. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tEuropean Journal of Organic Chemistry | ||
| 463 |
_tVol. 2018, iss. 45 _v[P. 6199-6203] _d2018 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aacylnitroso | |
| 610 | 1 | _acatalysis | |
| 610 | 1 | _acycloaddition | |
| 610 | 1 | _aene reaction iodine | |
| 610 | 1 | _aкатализ | |
| 610 | 1 | _aциклоприсоединение | |
| 701 | 1 |
_aUraoka _bS. _gSaki |
|
| 701 | 1 |
_aShinohara _bI. _gIkumi |
|
| 701 | 1 |
_aShimizu _bH. _gHisato |
|
| 701 | 1 |
_aNoguchi _bK. _gKeiichi |
|
| 701 | 1 |
_aYoshimura _bA. _cchemical engineer _cProfessor of Tomsk Polytechnic University _f1981- _gAkira _2stltpush _3(RuTPU)RU\TPU\pers\39852 |
|
| 701 | 1 |
_aZhdankin _bV. V. _cхимик _cProfessor of Tomsk Polytechnic University, Doctor of chemical sciences _f1956- _gViktor Vladimirovich _2stltpush _3(RuTPU)RU\TPU\pers\35758 |
|
| 701 | 1 |
_aSaito _bA. _gAkio |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИсследовательская школа химических и биомедицинских технологий (ИШХБМТ) _c(2017- ) _h8120 _2stltpush _3(RuTPU)RU\TPU\col\23537 |
| 801 | 2 |
_aRU _b63413507 _c20201111 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.1002/ejoc.201801340 | |
| 942 | _cCF | ||