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101 0 _aeng
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aOil-Filled Cryogels: New Approach for Storage and Utilization of Liquid Combustible Wastes
_fK. Yu. Vershinina [et al.]
203 _aText
_celectronic
300 _aTitle screen
330 _aA method of preparing oil-filled cryogels on the basis of an aqueous solution of poly(vinyl alcohol) (PVA) has been elaborated. The stability of primary oil emulsions and their rheological properties were analyzed for 30 days, as well as the mechanical properties of gel fuel pellets (obtained after 15 cycles of freezing/thawing of oil emulsions) with size of 20 mm for a group of compositions: 100–20 vol % aqueous solution of PVA (5, 10 wt %) + 0–80 vol % oil. The rheological behavior of non-Newtonian oil emulsions is described by the Herschel–Bulkley model. The elastic moduli and the tensile strength of fuel pellets of different component compositions range from 0.7 to 7.6 kPa and from 2.5 to 60 kPa, respectively. The oleophilic properties are more distinct for gel fuel prepared from oil emulsions with a higher content of the dispersed phase and lower concentrations of the polymer in the dispersion medium. The ignition mechanism and combustion characteristics have been established for processes occurring under the conditions of a radiant heat supply. Gel fuels, unlike combustible liquids, are characterized by a longer induction period, but a multicomponent structure of fuel caused microexplosions that enhance the combustion process.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tIndustrial and Engineering Chemistry Research
463 _tVol. 58, iss. 16
_v[P. 6830-6840]
_d2019
610 1 _aтруды учёных ТПУ
610 1 _aэлектронный ресурс
610 1 _aкриогели
610 1 _aутилизация
610 1 _aгорючие отходы
701 1 _aVershinina
_bK. Yu.
_cspecialist in the field of heat and power engineering
_claboratory assistant of Tomsk Polytechnic University
_f1992-
_gKseniya Yurievna
_2stltpush
_3(RuTPU)RU\TPU\pers\33706
701 1 _aGlushkov
_bD. O.
_cspecialist in the field of power engineering
_cAssociate Professor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences
_f1988-
_gDmitry Olegovich
_2stltpush
_3(RuTPU)RU\TPU\pers\32471
701 1 _aNigay
_bA. G.
_cspecialist in the field of informatics and computer technology
_cengineer of Tomsk Polytechnic University
_f1992-
_gAleksandr Gerasimovich
_2stltpush
_3(RuTPU)RU\TPU\pers\37189
701 1 _aYanovsky
_bV. A.
_gVyacheslav Aleksadrovich
701 1 _aYashutina
_bO. S.
_cspecialist in the field of heat and power engineering
_cResearch Engineer of Tomsk Polytechnic University
_f1993-
_gOlga Sergeevna
_2stltpush
_3(RuTPU)RU\TPU\pers\44658
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИсследовательская школа физики высокоэнергетических процессов
_c(2017- )
_h8118
_2stltpush
_3(RuTPU)RU\TPU\col\23551
801 2 _aRU
_b63413507
_c20191002
_gRCR
856 4 _uhttps://doi.org/10.1021/acs.iecr.9b00580
942 _cCF