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035 _aRU\TPU\network\31200
090 _a660998
100 _a20191115a2019 k y0engy50 ba
101 0 _aeng
102 _aNL
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aHigh resolution analysis of GeH4 in the dyad region: Ro-vibration energy structure of 70GeH4 and line strengths of MGeH4 (M = 70, 72, 73, 74, 76)
_fO. N. Ulenekov (Ulenikov) [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 109 tit.]
330 _aThe infrared spectrum of MGeH4 (M=70,72,73,74,76) was measured at the temperature of (294.5 ± 0.3) K in the 740-960 cm−1 region with a Bruker Fourier transform infrared spectrometer IFS125 and analyzed. The line positions of the ν2/ν4 bands and the ro-vibrational energy structure of corresponding upper vibrational states of 70GeH4 were analyzed. The strengths of 1079 experimentally recorded spectral lines (243/270/152/262/152 lines for the isotopologues 70GeH4/72GeH4/73GeH4/ 74GeH4/76GeH4) with the value of quantum number Jmax = 19 were determined from the fit of their line shapes with a Hartmann-Tran line profile and were used then in the weighted fit for determination of the effective dipole moment parameters of the ν4 band. The obtained sets of parameters reproduce the initial experimental line intensities with the drms=3.46/3.12/3.21/3.38/3.45/% for the 70GeH4/72GeH4/73GeH4/ 74GeH4/76GeH4 species, respectively. A list of transitions with their line intensities is generated in the HITRAN format up to the value of quantum number J=40.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tJournal of Quantitative Spectroscopy and Radiative Transfer
463 _tVol. 236
_v[106581, 14 p.]
_d2019
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
701 1 _aUlenekov (Ulenikov)
_bO. N.
_cphysicist
_cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences
_f1949-
_gOleg Nikolaevich
_2stltpush
_3(RuTPU)RU\TPU\pers\34331
701 1 _aGromova
_bO. V.
_cphysicist
_cProfessor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences
_f1982-
_gOlga Vasilievna
_2stltpush
_3(RuTPU)RU\TPU\pers\34333
701 1 _aBekhtereva
_bE. S.
_cphysicist
_cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences
_f1974-
_gElena Sergeevna
_2stltpush
_3(RuTPU)RU\TPU\pers\34450
701 1 _aRaspopova
_bN. I.
_cphysicist
_cTechnician of Tomsk Polytechnic University, Assistant of the Department
_f1990-
_gNatalya Ivanovna
_2stltpush
_3(RuTPU)RU\TPU\pers\34080
701 1 _aKuznetsov
_bA. V.
_cPhysicist
_cEngineer of Tomsk Polytechnic University
_f1994-
_gAlexey Valerevich
_2stltpush
_3(RuTPU)RU\TPU\pers\44420
701 1 _aSydow
_bC.
_gChristian
701 1 _aBauerecker
_bS.
_gSigurd
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИсследовательская школа физики высокоэнергетических процессов
_c(2017- )
_h8118
_2stltpush
_3(RuTPU)RU\TPU\col\23551
801 2 _aRU
_b63413507
_c20191115
_gRCR
856 4 _uhttps://doi.org/10.1016/j.jqsrt.2019.106581
942 _cCF