000 03565nlm1a2200529 4500
001 661206
005 20231030041738.0
035 _a(RuTPU)RU\TPU\network\31462
035 _aRU\TPU\network\29337
090 _a661206
100 _a20191122a2019 k y0engy50 ba
101 0 _aeng
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aProgress on Catalyst Development for Direct Synthesis of Dimethyl Carbonate from CO2 and Methanol
_fS. Chaemchuen [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 120 tit.]
330 _aThe reaction of carbon dioxide transformation is tremendously interesting in research societies from the viewpoint of carbon resource and also to resolve the environmental problem of carbon dioxide emission. Carbon dioxide (CO2) is a suitable C1 feedstock which can be converted into a number of valuable fine chemicals. The utilization of CO2 not only helps to reduce the carbon emission but should also lead to economic benefits, if CO2 is converted into chemicals for which there are significant demands or have a high added value. The reaction of CO2 with methanol is one of the pathways to directly synthesize dimethyl carbonate. However, the catalyst is a key factor in the reaction development. Herein, in this review, the focus is made on materials for the catalyzed reaction for the direct synthesis of dimethyl carbonate (DMC) from CO2 and methanol. The developed catalysts (homogeneous and heterogeneous catalysts) used so far are discussed, together with the respective operating conditions to obtain the optimum catalyst performance. Interesting ideas to allow the direct synthesis of carbonate products from CO2 with methanol using developed novel catalysts with high performance and efficiency for the economy are offered in this review.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tChemistry Africa
463 _tVol. 2, iss 4
_v[P. 533-549]
_d2019
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _adimethyl carbonate
610 1 _alinear carbonate
610 1 _acatalyst
610 1 _acatalyst
610 1 _aCO2 utilization
610 1 _amethanol
610 1 _aкарбонаты
610 1 _aкатализаторы
610 1 _aутилизация
610 1 _aуглекислый газ
610 1 _aметанолы
701 0 _aChaemchuen
_bS.
_cchemist-technologist
_cresearcher at Tomsk Polytechnic University
_f1984-
_gSomboon
_2stltpush
_3(RuTPU)RU\TPU\pers\42620
701 1 _aSemyonov
_bO. V.
_cprocess chemist
_cJunior Researcher, Tomsk Polytechnic University
_f1993-
_gOleg Vladimirovich
_2stltpush
_3(RuTPU)RU\TPU\pers\45298
701 0 _aDingemans Jannes
701 0 _aXu Wei
701 0 _aKhan Anish
701 1 _aVerpoort
_bF. V. K.
_cChemical Engineer
_cProfessor of Tomsk Polytechnic University, doctor of chemical Sciences
_f1963-
_gFrensis Valter Kornelius
_2stltpush
_3(RuTPU)RU\TPU\pers\35059
701 0 _aZhuiykov
_bS.
_gSerge
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИсследовательская школа химических и биомедицинских технологий
_c(2017- )
_h8120
_2stltpush
_3(RuTPU)RU\TPU\col\23537
801 2 _aRU
_b63413507
_c20191125
_gRCR
856 4 _uhttps://doi.org/10.1007/s42250-019-00082-x
942 _cCF