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100 _a20200122a2019 k y0engy50 ba
101 0 _aeng
102 _aNL
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aThe effect of chromium concentration on luminescent properties of alkali-alumina-borate glass-ceramics
_fA. I. Babkina [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 36 tit.]
330 _aAlkali alumina-borate glass-ceramics doped with different concentration of Cr3+ ions was prepared by conventional melt-quenching technique. Luminescent glass-ceramics was derived by volume crystallization of the precursor glass via two-stage heat treatment. The phase transition temperatures, structure, spectral and luminescent properties of the glass-ceramics were determined by differential scanning calorimetry (DSC), X-ray diffraction (XRD), optical absorption, photo- and cathodoluminescent spectroscopy. The XRD studies revealed the LiAl7B4O17: Cr3+ nanocrystals nucleation (mean size of 20–23?nm) during the heat treatment. The photoluminescence spectra consisted of three intense bands in the 685–715?nm region. The maximum quantum yield value under 532?nm excitation was 30%. The difference between photoluminescence (PL) and cathodoluminescence (CL) decay kinetics is presented and possible nature of this phenomenon is discussed.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tJournal of Non-Crystalline Solids
463 _tVol. 521
_v[119487, 7 p.]
_d2019
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _aстекло
610 1 _aкатодолюминесценция
610 1 _aионы
610 1 _aраспады
610 1 _aalkali alumina-borate glass
610 1 _aluminescent glass-ceramics
610 1 _atrivalent chromium ions
610 1 _aphotoluminescence
610 1 _acatodoluminescence
610 1 _adecay kinetics
701 1 _aBabkina
_bA. I.
_gAlyona Igorevna
701 1 _aZyrjyanova
_bK. S.
_gKseniya Sergeevna
701 1 _aAgafonova
_bD. S.
_gDarjya Andreevna
701 1 _aNuryev
_bR. K.
_gRustam Kakabaevich
701 1 _aIgnatjev
_bA. I.
_gAndrey Ivanovich
701 1 _aValiev
_bD. T.
_cspecialist in the field of material science
_cAssociate Professor of Tomsk Polytechnic University, Candidate of Sciences
_f1987-
_gDamir Talgatovich
_2stltpush
_3(RuTPU)RU\TPU\pers\33772
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИнженерная школа новых производственных технологий
_bОтделение материаловедения
_h7871
_2stltpush
_3(RuTPU)RU\TPU\col\23508
801 2 _aRU
_b63413507
_c20200122
_gRCR
856 4 _uhttps://doi.org/10.1016/j.jnoncrysol.2019.119487
942 _cCF