| 000 | 02901nlm1a2200409 4500 | ||
|---|---|---|---|
| 001 | 661964 | ||
| 005 | 20231030041805.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\33075 | ||
| 090 | _a661964 | ||
| 100 | _a20200325a2019 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aOxidative addition of verdazyl halogenides to Pd(PPh3)4 _fP. V. Petunin, D. E. Votkina, M. E. Trusova [et al.] |
|
| 203 |
_aText _celectronic |
||
| 300 | _aTitle screen | ||
| 330 | _aDirect oxidative addition of verdazyl halogenides to Pd(0) was studied and the role of this step in the Pd-catalyzed cross-coupling reactions was evaluated. A number of bis(triphenylphosphine)[verdazyl]palladium(II) iodide species were synthesized in yields of 89 to 92% and were shown to be persistent under ambient conditions. High synthetic potential of Pd-verdazyls was demonstrated by their efficiency and reactivity in the Sonogashira coupling reaction. These derivatives significantly expand the modern synthetic tools for development of spin-labeled materials and polyradical systems with desired functionalities. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tNew Journal of Chemistry | ||
| 463 |
_tVol. 43, iss. 38 _v[P. 15293-15301] _d2019 |
||
| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aокислительное присоединение | |
| 701 | 1 |
_aPetunin _bP. V. _cchemist _cEngineer of Tomsk Polytechnic University _f1982- _gPavel Vasilievich _2stltpush _3(RuTPU)RU\TPU\pers\36904 |
|
| 701 | 1 |
_aVotkina _bD. E. _cchemical engineer _cEngineer of the Tomsk Polytechnic University _f1995- _gDarjya Evgenjevna _2stltpush _3(RuTPU)RU\TPU\pers\45598 |
|
| 701 | 1 |
_aTrusova _bM. E. _corganic chemist _cAssociate professor of Tomsk Polytechnic University, Candidate of chemical sciences _f1982- _gMarina Evgenievna _2stltpush _3(RuTPU)RU\TPU\pers\31823 |
|
| 701 | 1 |
_aRybalova _bT. V. _gTatjyana Valerjevna |
|
| 701 | 1 |
_aAmosov _bE. V. _gEvgeny Valerjevich |
|
| 701 | 1 |
_aUvarov _bM. N. _gMikhail Nikolaevich |
|
| 701 | 1 |
_aPostnikov _bP. S. _corganic chemist _cAssociate Professor of Tomsk Polytechnic University, Candidate of chemical sciences _f1984- _gPavel Sergeevich _2stltpush _3(RuTPU)RU\TPU\pers\31287 |
|
| 701 | 1 |
_aKazantsev _bM. S. _gMaksim Sergeevich |
|
| 701 | 1 |
_aMostovich _bE. A. _gEvgeny Alekseevich |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИсследовательская школа химических и биомедицинских технологий (ИШХБМТ) _c(2017- ) _h8120 _2stltpush _3(RuTPU)RU\TPU\col\23537 |
| 801 | 2 |
_aRU _b63413507 _c20200325 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.1039/C9NJ03361K | |
| 942 | _cCF | ||