000 04333nlm1a2200445 4500
001 662047
005 20231030041808.0
035 _a(RuTPU)RU\TPU\network\33180
090 _a662047
100 _a20200512a2019 k y0engy50 ba
101 0 _aeng
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aEffects of the Initial Gel Fuel Temperature on the Ignition Mechanism and Characteristics of Oil-Filled Cryogel Droplets in the High-Temperature Oxidizer Medium
_fD. O. Glushkov, A. G. Nigay, V. A. Yanovsky, O. S. Yashutina
203 _aText
_celectronic
300 _aTitle screen
330 _aThe ignition mechanism was studied for a group of gel fuel compositions in a high-temperature oxidizer medium. It was determined how the initial temperature of the fuel influences the ignition characteristics. The gel fuel (oil-filled cryogel) was prepared from an oil emulsion based on the mixture of a combustible liquid and polyvinyl alcohol. The composition of primary oil emulsions was as follows: the aqueous solution of polyvinyl alcohol (5, 10 wt %) + 40-60 vol % of oil + 2 vol % of emulsifier. The initial temperature of gel fuels ranged from 188 to 293 K. Combustion was initiated in high-temperature motionless air at 873-1273 K. Using a high-speed video recording system, we established that at different initial temperatures of the gel fuel, a set of identical processes occurs during the induction period; these are different from the same physical and chemical processes during the ignition of a combustible liquid. After reaching threshold conditions, the flame spreads in the droplet's vicinity from a hot spot through the gas mixture. Hot spot is an ignited and a small-sized fragment separating and moving away from the molten fuel droplet as a result of a microexplosion. The values of the main process characteristic - ignition delay times - differ 25-95% for fuel samples with the initial temperature of 293 K and temperatures of 188-233 K because of a long heating and melting stage of the latter. This is explained by a 2.5-3.6-fold difference in the amount of energy, which is necessary to supply to a colder fuel sample for this phase transformation to occur, other things being equal.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tEnergy and Fuels
463 _tVol. 33, iss. 11
_v[P. 11812-11820]
_d2019
610 1 _aтруды учёных ТПУ
610 1 _aэлектронный ресурс
610 1 _aredox reactions
610 1 _aliquids
610 1 _afossil fuels
610 1 _agels
610 1 _aокислительно-восстановительные реакции
610 1 _aжидкости
610 1 _aископаемое топливо
610 1 _aгели
701 1 _aGlushkov
_bD. O.
_cspecialist in the field of power engineering
_cAssociate Professor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences
_f1988-
_gDmitry Olegovich
_2stltpush
_3(RuTPU)RU\TPU\pers\32471
701 1 _aNigay
_bA. G.
_cspecialist in the field of informatics and computer technology
_cengineer of Tomsk Polytechnic University
_f1992-
_gAleksandr Gerasimovich
_2stltpush
_3(RuTPU)RU\TPU\pers\37189
701 1 _aYanovsky
_bV. A.
_gVyacheslav Aleksadrovich
701 1 _aYashutina
_bO. S.
_cspecialist in the field of heat and power engineering
_cResearch Engineer of Tomsk Polytechnic University
_f1993-
_gOlga Sergeevna
_2stltpush
_3(RuTPU)RU\TPU\pers\44658
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИнженерная школа энергетики
_bНаучно-образовательный центр И. Н. Бутакова (НОЦ И. Н. Бутакова)
_h8025
_2stltpush
_3(RuTPU)RU\TPU\col\23504
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИсследовательская школа физики высокоэнергетических процессов
_c(2017- )
_h8118
_2stltpush
_3(RuTPU)RU\TPU\col\23551
801 2 _aRU
_b63413507
_c20200512
_gRCR
856 4 _uhttps://doi.org/10.1021/acs.energyfuels.9b02300
942 _cCF