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100 _a20200604a2020 k y0engy50 ba
101 0 _aeng
102 _aUS
135 _adrcn ---uucaa
181 0 _ai
182 0 _ab
200 1 _aKinetic Characteristics of the Oxidation of Non-Food Municipal Solid Waste
_fK. B. Larionov, S. A. Tsibulskii (Tsibulskiy), K. V. Slusarskiy (Slyusarsky) [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 14 tit.]
330 _aThe kinetic characteristics of the oxidation of non-food municipal MSW (MSW) were studied. Energetically valuable components of non-food MSW (sawdust, plastics, cardboard, textiles, leather, and rubber) were used as test samples. The elemental composition and technical characteristics of the test samples were determined using an elemental analyzer and standard procedures. The thermal conversion of non-food MSW was carried out using thermogravimetric analysis in the oxidation mode at a heating rate of 10 K/min in a temperature range of 25–800°C at atmospheric pressure. According to thermal analysis data (DTG curves), the process stages of the oxidation of non-food MSW, which correspond to the mono- or bimodal evolution of volatile compounds and the oxidation of the resulting carbon residue, were determined. The qualitative analysis of the gas-phase products of non-food MSW oxidation was performed by mass spectrometry, and the results were compared with the elemental composition and technical characteristics of the test samples. The activation energies of the stages of non-food MSW oxidation were calculated using the Coats–Redfern method. The maximum value of Ea (114.7 kJ/mol) was observed in a plastic sample, the decomposition of which tentatively proceeded in a single stage.
333 _aРежим доступа: по договору с организацией-держателем ресурса
461 _tSolid Fuel Chemistry
463 _tVol. 54, iss. 1
_v[P. 54-60]
_d2020
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _anon-food municipal solid waste (MSW)
610 1 _ainitial temperature of intense oxidation
610 1 _aactivation energy
610 1 _athermogravimetric analysis
610 1 _amass-spectrometric analysis
610 1 _aтвердые отходы
610 1 _aбытовые отходы
610 1 _aокисление
610 1 _aтермогравиметрический анализ
610 1 _aмасс-спектрометрический анализ
701 1 _aLarionov
_bK. B.
_cspecialist in the field of power engineering
_ctechnician of Tomsk Polytechnic University
_f1990-
_gKirill Borisovich
_2stltpush
_3(RuTPU)RU\TPU\pers\35705
701 1 _aTsibulskii (Tsibulskiy)
_bS. A.
_cspecialist in the field of power engineering
_cAssistant of Tomsk Polytechnic University
_f1990-
_gSvyatoslav Anatolievich
_2stltpush
_3(RuTPU)RU\TPU\pers\34297
701 1 _aSlusarskiy (Slyusarsky)
_bK. V.
_cspecialist in the field of power engineering
_cassistant of Tomsk Polytechnic University
_f1990-
_gKonstantin Vitalievich
_2stltpush
_3(RuTPU)RU\TPU\pers\35634
701 1 _aVedyagin
_bA. A.
_cChemist
_cChief Expert of Tomsk Polytechnic University, Candidate of chemical sciences
_f1975-
_gAleksey Anatolievich
_2stltpush
_3(RuTPU)RU\TPU\pers\36694
701 1 _aGubin
_bV. E.
_cspecialist in the field of power engineering
_cAssociate Professor of Tomsk Polytechnic University, Candidate of technical sciences
_f1976-
_gVladimir Evgenievich
_2stltpush
_3(RuTPU)RU\TPU\pers\35120
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИнженерная школа энергетики
_bНаучно-образовательный центр И. Н. Бутакова (НОЦ И. Н. Бутакова)
_h8025
_2stltpush
_3(RuTPU)RU\TPU\col\23504
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИсследовательская школа химических и биомедицинских технологий
_c(2017- )
_h8120
_2stltpush
_3(RuTPU)RU\TPU\col\23537
801 2 _aRU
_b63413507
_c20200604
_gRCR
856 4 _uhttps://doi.org/10.3103/S036152192001005X
942 _cCF