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101 0 _aeng
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181 0 _ai
182 0 _ab
200 1 _aA Trace Element Classification Tree for Chalcopyrite from Oktyabrsk Deposit, Norilsk–Talnakh Ore District, Russia: LA-ICPMS Study
_fA. E. Marfin, A. V. Ivanov, V. D. Abramova [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 53 tit.]
330 _aThe Oktyabrsk PGE-Cu-Ni deposit is one of the largest resources in the Norilsk–Talnakh ore district, Russia, and it is viewed as an ore giant on a global scale. It contains three types of ores: massive, disseminated and veinlet-disseminated. The two former ore types were formed by a liquation process, whereas the latter was associated with fluid-induced selective metasomatic replacement of metamorphosed wall rocks. One of the major ore minerals in all ore types is chalcopyrite. In this study, we determined concentrations of trace elements in this mineral using laser ablation inductively coupled plasma mass spectrometry. It appeared that standard geochemical tools, such as plotting the data in the form of diagrams of normalized concentrations, binary and ternary plots, do not allow one to distinguish chalcopyrite from visually and genetically different ore types. In contrast, more advanced statistical methods such as cluster analysis show different groupings of elements for each ore type. Based on the element clustering, a classification tree was suggested, which allowed for the differentiation of massive, disseminated and veinlet-disseminated ore types of the Oktyabrsk deposit by Se, Te, Cd and Pb concentrations in chalcopyrite with a success rate of 86%. The general feature is that chalcopyrite of veinlet-disseminated ore is poorer in these elements compared to chalcopyrite of the two other ore types. Chalcopyrite of massive ore is poorer in Se and Te when compared to chalcopyrite of disseminated ore.
461 _tMinerals
463 _tVol. 10, iss. 8
_v[716, 15 p.]
_d2020
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _aTalnakh
610 1 _aSiberian flood basalts
610 1 _aLA-ICPMS
610 1 _asulfide
610 1 _achalcopyrite
610 1 _acluster analysis
610 1 _aclassification tree
610 1 _aТалнахское месторождение
610 1 _aбазальты
610 1 _aсульфиды
610 1 _aхалькопирит
610 1 _aкластерный анализ
701 1 _aMarfin
_bA. E.
_gAleksandr Evgenjevich
701 1 _aIvanov
_bA. V.
_gAleksey
701 1 _aAbramova
_bV. D.
_gVera
701 1 _aAnziferova
_bT. N.
_gTatiana
701 1 _aRadomskaya
_bT. A.
_gTatiana
701 1 _aYakich
_bT. Yu.
_cgeologist
_cAssociate Professor of Tomsk Polytechnic University, Candidate of geological and mineralogical sciences
_f1984-
_gTamara Yurievna
_2stltpush
_3(RuTPU)RU\TPU\pers\43279
701 1 _aBestemianova
_bK. V.
_gKsenia
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИнженерная школа природных ресурсов
_bОтделение геологии
_h8083
_2stltpush
_3(RuTPU)RU\TPU\col\23542
801 2 _aRU
_b63413507
_c20200820
_gRCR
856 4 _uhttps://doi.org/10.3390/min10080716
942 _cCF