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| 090 | _a662544 | ||
| 100 | _a20200902a2020 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aNL | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aComprehensive ro-vibrational analysis of di-deuterated hydrogen sulfide in the region of the ν2, 2ν2 and 2ν2−ν2 bands: The D232S, D234S, and D233S isotopologues _fO. N. Ulenekov (Ulenikov), E. S. Bekhtereva, O. V. Gromova [et al.] |
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| 203 |
_aText _celectronic |
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| 300 | _aTitle screen | ||
| 320 | _a[References: 80 tit.] | ||
| 330 | _aHigh–resolution infrared spectra of the D2S molecule were experimentally recorded with a Bruker IFS 125HR Fourier transform infrared spectrometer and theoretically analyzed in the region of 700 – 1800?cm where the ?2 and 2?2 bands are located. For the first time, transitions were assigned to the 2?2 and bands of the D232S and D234S isotopologues. For the ground vibrational state and the ?2 band of D234S, the spectral information was considerably extended in comparison with preceding works. For the first time, transitions belonging to the rare D233S hydrogen sulfide species were assigned to the ?2 and 2?2 bands, as well as a rotational structure of the ground vibrational state of D233S was determined on the basis of experimental values of the ground state combination differences (maximum values of quantum numbers for used ground state combination differences were ). Sets of spectroscopic parameters of the Watson hamiltonian in reduction and representation was determined for the (010) and (020) vibrational states of all three discussed species and for the ground vibrational states of D234S and D233S from the weighted fit of parameters of this hamiltonian. The drms of reproduction of the initial experimental data for all nine vibrational states (three vibrational states for any species) is not far from cm which is close to experimental errors in line positions. | ||
| 333 | _aРежим доступа: по договору с организацией-держателем ресурса | ||
| 461 | _tJournal of Quantitative Spectroscopy and Radiative Transfer | ||
| 463 |
_tVol. 252 _v[107106, 17 p.] _d2020 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _aсероводород | |
| 701 | 1 |
_aUlenekov (Ulenikov) _bO. N. _cphysicist _cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences _f1949- _gOleg Nikolaevich _2stltpush _3(RuTPU)RU\TPU\pers\34331 |
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| 701 | 1 |
_aBekhtereva _bE. S. _cphysicist _cProfessor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences _f1974- _gElena Sergeevna _2stltpush _3(RuTPU)RU\TPU\pers\34450 |
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| 701 | 1 |
_aGromova _bO. V. _cphysicist _cProfessor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences _f1982- _gOlga Vasilievna _2stltpush _3(RuTPU)RU\TPU\pers\34333 |
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| 701 | 1 |
_aErsin _bЕю Ую _gTolganay Ersinkyzy |
|
| 701 | 1 |
_aSydow _bCh. _gChristian |
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| 701 | 1 |
_aMaul _bG. K. _gGans Kristof |
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| 701 | 1 |
_aBauerekker (Bauerekker) _bZ. K. _gZigurd Khermann |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИсследовательская школа физики высокоэнергетических процессов _c(2017- ) _h8118 _2stltpush _3(RuTPU)RU\TPU\col\23551 |
| 801 | 2 |
_aRU _b63413507 _c20200902 _gRCR |
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| 856 | 4 | _uhttps://doi.org/10.1016/j.jqsrt.2020.107106 | |
| 942 | _cCF | ||