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182 0 _ab
200 1 _aStructural and Spectroscopic Characterization of Tb3+-Doped MgAl2O4 Spinel Ceramics Fabricated by Spark Plasma Sintering Technique
_fD. T. Valiev, O. L. Khasanov, E. S. Dvilis [et al.]
203 _aText
_celectronic
300 _aTitle screen
320 _a[References: 44 tit.]
330 _aSpark plasma sintering (SPS) technique is successfully used for the preparation of magnesium aluminate spinel ceramics doped with different concentrations of Tb3+ ions. Structural, morphological, optical, and photoluminescence (PL) characterization are conducted. It is demonstrated that the redshift in the absorption spectra is possibly due to the energy gap between the valence and conduction bands reducing and the formation of a higher concentration of nonbridging oxygen with an increase in the concentrations of Tb3+ ions in MgAl2O4 ceramics. The PL spectrum excited by nitrogen laser consists of a broad emission band with a maximum at ?em?˜?400?nm and a series of emission bands in the 400–700?nm spectral range responsible for Tb3+ ions. In the “blue” spectral region, the complex host centers such as oxygen vacancies are recorded. An increase in the terbium ion concentration does not lead to the effect of concentration quenching. Luminescence decay kinetics analysis for all ceramics samples is performed. The effect of terbium oxide on the optical, PL properties and luminescence decay kinetics of MgAl2O4 ceramics is discussed.
461 _tPhysica Status Solidi (B)
463 _tVol. 257, iss. 8
_v[1900471, 6 p.]
_d2020
610 1 _aэлектронный ресурс
610 1 _aтруды учёных ТПУ
610 1 _aceramics
610 1 _aluminescence properties
610 1 _amagnesium aluminum spinel
610 1 _aspark plasma sintering technique
610 1 _aterbium ions
610 1 _aкерамика
610 1 _aлюминесцентные свойства
610 1 _aмагниево-алюминиевые соединения
610 1 _aплазменное спекание
610 1 _aионы тербия
701 1 _aValiev
_bD. T.
_cspecialist in the field of material science
_cAssociate Professor of Tomsk Polytechnic University, Candidate of Sciences
_f1987-
_gDamir Talgatovich
_2stltpush
_3(RuTPU)RU\TPU\pers\33772
701 1 _aKhasanov
_bO. L.
_cRussian physicist, materials scientist, Doctor of Engineering
_cprofessor, Director of TPU Nano-Centre and Head of the Department "Nanomaterials and Nanotechnologies" of TPU
_f1958-
_gOleg Leonidovich
_2stltpush
_3(RuTPU)RU\TPU\pers\27102
701 1 _aDvilis
_bE. S.
_cChemical Engineer
_csenior researcher of Tomsk Polytechnic University, Professor, doctor of physical and mathematical Sciences
_f1969-
_gEdgar Sergeevich
_2stltpush
_3(RuTPU)RU\TPU\pers\34597
701 1 _aStepanov
_bS. A.
_cspecialist in the field of lightning engineering
_cEngineer of Tomsk Polytechnic University
_f1986-
_gSergey Aleksandrovich
_2stltpush
_3(RuTPU)RU\TPU\pers\33771
701 1 _aPaygin
_bV. D.
_cspecialist in the field of material science
_cengineer of Tomsk Polytechnic University
_f1992-
_gVladimir Denisovich
_2stltpush
_3(RuTPU)RU\TPU\pers\38492
701 1 _aIlela
_bA. E.
_cspecialist in the field of material science
_cAssistant of the Department of Tomsk Polytechnic University
_f1982-
_gAlfa Edison
_2stltpush
_3(RuTPU)RU\TPU\pers\42538
712 0 2 _aНациональный исследовательский Томский политехнический университет
_bИнженерная школа новых производственных технологий
_bОтделение материаловедения
_h7871
_2stltpush
_3(RuTPU)RU\TPU\col\23508
801 2 _aRU
_b63413507
_c20200908
_gRCR
856 4 _uhttps://doi.org/10.1002/pssb.201900471
942 _cCF