| 000 | 03719nlm1a2200601 4500 | ||
|---|---|---|---|
| 001 | 663826 | ||
| 005 | 20231030041909.0 | ||
| 035 | _a(RuTPU)RU\TPU\network\34996 | ||
| 035 | _aRU\TPU\network\34421 | ||
| 090 | _a663826 | ||
| 100 | _a20210311a2020 k y0engy50 ba | ||
| 101 | 0 | _aeng | |
| 102 | _aCH | ||
| 135 | _adrcn ---uucaa | ||
| 181 | 0 | _ai | |
| 182 | 0 | _ab | |
| 200 | 1 |
_aGlycerol Oxidation over Supported Gold Catalysts: The Combined Effect of Au Particle Size and Basicity of Support _fE. G. Pakrieva, E. N. Kolobova, D. Yu. German [et al.] |
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| 203 |
_aText _celectronic |
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| 300 | _aTitle screen | ||
| 320 | _a[References: 47 tit.] | ||
| 330 | _aGold nanoparticles supported on various oxides (CeO2, CeO2/TiO2, MgO, MgO/TiO2, La2O3, La2O3/TiO2) (with 4 wt.% Au loading) were investigated in the liquid (aqueous) phase oxidation of glycerol by molecular oxygen under mild conditions, in the presence of alkaline earth (CaO, SrO and MgO) or alkaline (NaOH) bases. Full conversion and selectivity between 38 and 68% to sodium glycerate were observed on different Au supported catalysts (Au/MgO/TiO2, Au/La2O3/TiO2, Au/CeO2 and Au/CeO2/TiO2). The combined effect of Au particle size and basicity of the support was suggested as the determining factor of the activity. Agglomeration of gold nanoparticles, found after the reaction, led to the deactivation of the catalysts, which prevents the further oxidation of sodium glycerate into sodium tartronate. Promising results were obtained with the use of alkaline earth bases (CaO, SrO, MgO), leading to the formation of free carboxylic acids instead of salts, which are formed in the presence of the more usual base, NaOH. | ||
| 338 |
_bРоссийский фонд фундаментальных исследований _d18-29-24037 |
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| 461 | _tProcesses | ||
| 463 |
_tVol. 8, iss. 9 _v[1016, 17 p.] _d2020 |
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| 610 | 1 | _aэлектронный ресурс | |
| 610 | 1 | _aтруды учёных ТПУ | |
| 610 | 1 | _agold catalysts | |
| 610 | 1 | _aglycerol oxidation | |
| 610 | 1 | _acatalyst selectivity | |
| 610 | 1 | _aglyceric acid | |
| 610 | 1 | _atartronicacid | |
| 610 | 1 | _abase additives | |
| 610 | 1 | _aкатализаторы | |
| 610 | 1 | _aокисление | |
| 610 | 1 | _aглицерин | |
| 610 | 1 | _aселективность | |
| 610 | 1 | _aкислоты | |
| 610 | 1 | _aдобавки | |
| 610 | 1 | _aзолото | |
| 701 | 1 |
_aPakrieva _bE. G. _cChemical Engineer _cEngineer of Tomsk Polytechnic University _f1989- _gEkaterina Germanovna _2stltpush _3(RuTPU)RU\TPU\pers\33273 |
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| 701 | 1 |
_aKolobova _bE. N. _cChemical Engineer _cdesign engineer of Tomsk Polytechnic University _f1989- _gEkaterina Nikolaevna _2stltpush _3(RuTPU)RU\TPU\pers\34488 |
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| 701 | 1 |
_aGerman _bD. Yu. _cChemical engineer _cEngineer of Tomsk Polytechnic University _f1993- _gDmitry Yuryevich _2stltpush _3(RuTPU)RU\TPU\pers\42480 |
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| 701 | 1 |
_aStucchi _bM. _gMarta |
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| 701 | 1 |
_aVilla _bA. _gAlberto |
|
| 701 | 1 |
_aPrati _bL. _gLaura |
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| 701 | 1 |
_aCarabineiro _bS. A. C. _gSonia Alexandra Correia |
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| 701 | 1 |
_aBogdanchikova _bN. _gNina |
|
| 701 | 1 |
_aCorberan _bV. C. _gCortes |
|
| 701 | 1 |
_aPestryakov _bA. N. _cChemist _cProfessor of Tomsk Polytechnic University, Doctor of Chemical Science _f1963- _gAleksey Nikolaevich _2stltpush _3(RuTPU)RU\TPU\pers\30471 |
|
| 712 | 0 | 2 |
_aНациональный исследовательский Томский политехнический университет _bИсследовательская школа химических и биомедицинских технологий _c(2017- ) _h8120 _2stltpush _3(RuTPU)RU\TPU\col\23537 |
| 801 | 2 |
_aRU _b63413507 _c20210311 _gRCR |
|
| 856 | 4 | _uhttps://doi.org/10.3390/pr8020217 | |
| 942 | _cCF | ||